(S)-3,3'-bis(4-Methoxyphenyl)-[1,1'-Binaphthalene]-2,2'-diol

Base Information

• Chemical Name: (S)-3,3'-bis(4-Methoxyphenyl)-[1,1'-Binaphthalene]-2,2'-diol
• CAS No.: 1199631-29-2
• Molecular Formula: C34H26O4
• Molecular Weight: 498.56784
• Mol file: 1199631-29-2.mol

Synonyms:(S)-3,3'-bis(4-Methoxyphenyl)-[1,1'-Binaphthalene]-2,2'-diol

Chemical Property of (S)-3,3'-bis(4-Methoxyphenyl)-[1,1'-Binaphthalene]-2,2'-diol

Chemical Property:

• Boiling Point: 624.7±55.0 °C(Predicted)
• PKA: 8.20±0.50(Predicted)
• PSA: 58.92000
• Density: 1.251±0.06 g/cm3(Predicted)
• LogP: 8.42240

Purity/Quality:

98.5% ^*data from raw suppliers

(S)-3,3'-Bis(4-methoxyphenyl)-[1,1'-binaphthalene]-2,2'-diol 98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (S)-3,3'-bis(4-Methoxyphenyl)-[1,1'-Binaphthalene]-2,2'-diol

There total 24 articles about (S)-3,3'-bis(4-Methoxyphenyl)-[1,1'-Binaphthalene]-2,2'-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

(R)-3,3'-bis(4-methoxyphenyl)-2,2'-bis(methoxymethoxy)-1,1'-binaphthyl → (R)-(+)-3,3'-bis(4-methoxyphenyl)-[1,1'-binaphthalene]-2,2'-diol (1199631-29-2,756491-51-7)

Guidance literature:

With hydrogenchloride; In 1,4-dioxane; water; at 60 ℃; for 12h;

DOI:10.1039/d1ta07449k

Reference yield: 92.0%

potassium 4-(methoxy)phenyltrifluoroborate + (R)-3,3'-diiodo-2,2'-dihydroxy-1,1'-binaphthyl → (R)-(+)-3,3'-bis(4-methoxyphenyl)-[1,1'-binaphthalene]-2,2'-diol (1199631-29-2,756491-51-7)

Guidance literature:

With palladium on activated charcoal; potassium carbonate; In 1,4-dioxane; water; at 140 ℃; for 0.166667h; Microwave irradiation;

DOI:10.1016/j.tetlet.2014.09.109

Reference yield: 92.0%

2-(4-methoxyphenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (171364-79-7) + (R)-3,3'-diiodo-2,2'-dihydroxy-1,1'-binaphthyl → (R)-(+)-3,3'-bis(4-methoxyphenyl)-[1,1'-binaphthalene]-2,2'-diol (1199631-29-2,756491-51-7)

Guidance literature:

With palladium on activated charcoal; potassium carbonate; In 1,4-dioxane; water; at 140 ℃; for 0.166667h; Microwave irradiation;

DOI:10.1016/j.tetlet.2014.09.109

upstream raw materials:

(+/-)-3,3'-bis(4-methoxyphenyl)-2,2'-bis(methoxymethoxy)-1,1'-binaphthyl

rac-2,2'-bis-(methoxymethoxy)-1,1'-binaphthalene

(±)?3,3'?dibromo?2,2'?bis(methoxymethyl)?1,1'?binaphthalene

1,1'-bi-2-naphthol