Propynylboronic acid MIDA ester

Base Information

• Chemical Name: Propynylboronic acid MIDA ester
• CAS No.: 1104637-55-9
• Molecular Formula: C8H10BNO4
• Molecular Weight: 194.983
• Mol file: 1104637-55-9.mol

Synonyms:Propynylboronic acid MIDA ester;Propynylboronic acid MIDA ester 95%

Chemical Property of Propynylboronic acid MIDA ester

Chemical Property:

• PSA: 55.84000
• LogP: -0.99320

Purity/Quality:

98%,99%, ^*data from raw suppliers

PROPYNYLBORONIC ACID MIDA ESTER 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Suzuki Cross-Coupling with MIDA Boronates

Technology Process of Propynylboronic acid MIDA ester

There total 3 articles about Propynylboronic acid MIDA ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

N-methyliminodiacetic acid (4408-64-4) + BrMg(1+)*C6H12BO3(1-) → MeCCB(N-methyliminodiacetato) (1104637-55-9)

Guidance literature:

In tetrahydrofuran; dimethyl sulfoxide; at 105 - 115 ℃; Product distribution / selectivity; Inert atmosphere;

Reference yield: 19.0%

N-methyliminodiacetic acid (4408-64-4) + 1-butynyllithium (1119-18-2) → MeCCB(N-methyliminodiacetato) (1104637-55-9)

Guidance literature:

With Trimethyl borate; In tetrahydrofuran; hexane; dimethyl sulfoxide; at -65 - 115 ℃;

Reference yield:

C35H34B2N7O5PRu → {ruthenium(η3-tris(1-pyrazolyl)hydroborato)(triphenylphosphine)(carbonyl)(H)} + MeCCB(N-methyliminodiacetato) (1104637-55-9)

Guidance literature:

In chloroform-d1; for 24h; Inert atmosphere;

DOI:10.1039/c4dt03695f

upstream raw materials:

N-methyliminodiacetic acid

1-butynyllithium

Downstream raw materials:

6-methyl-2-vinyl-1,3,6,2-dioxazaborocane-4,8-dione