4-CARBOETHOXYPHENYL CYCLOPROPYL KETONE

Base Information

• Chemical Name: 4-CARBOETHOXYPHENYL CYCLOPROPYL KETONE
• CAS No.: 863769-67-9
• Molecular Formula: C13H14O3
• Molecular Weight: 218.252
• Hs Code.: 2914509090
• Mol file: 863769-67-9.mol

Synonyms:4-CARBOETHOXYPHENYL CYCLOPROPYL KETONE;ethyl 4-(cyclopropanecarbonyl)benzoate

Chemical Property of 4-CARBOETHOXYPHENYL CYCLOPROPYL KETONE

Chemical Property:

• Vapor Pressure: 3.71E-05mmHg at 25°C
• Boiling Point: 352.9°C at 760 mmHg
• Flash Point: 156.5°C
• PSA: 43.37000
• Density: 1.181g/cm³
• LogP: 2.45600

Purity/Quality:

97% ^*data from raw suppliers

4-Carboethoxyphenylcyclopropylketone 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-CARBOETHOXYPHENYL CYCLOPROPYL KETONE

There total 1 articles about 4-CARBOETHOXYPHENYL CYCLOPROPYL KETONE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ ethyl 4-(cyclopropylcarbonyl)benzoate (863769-67-9)

Guidance literature:

Reference yield: 87.0%

triethylsilane (617-86-7) + ethyl 4-(cyclopropylcarbonyl)benzoate (863769-67-9) → (Z)-4-(1-triethylsiloxy-1-butenyl)-benzoic acid ethyl ester (1190963-37-1)

Guidance literature:

With methanol; palladium diacetate; tricyclohexylphosphine; In toluene; at 60 ℃; for 10h; stereoselective reaction; Inert atmosphere;

DOI:10.1021/jo901513v

Reference yield: 59.0%

ethyl 4-(cyclopropylcarbonyl)benzoate (863769-67-9) + o-formylbenzonitrile (7468-67-9) + bis(4-bromophenyl)iodonium triflate (139139-81-4) → C27H22BrNO4

Guidance literature:

With copper diacetate; In 1,2-dichloro-ethane; at 110 ℃; for 0.5h; chemoselective reaction;

DOI:10.1021/acs.joc.8b01120

Downstream raw materials:

ethyl 4-(cyclopropyl(hydroxyl)methyl)benzoate

(Z)-4-(1-triethylsiloxy-1-butenyl)-benzoic acid ethyl ester

ethyl 4-[(1-methylcyclopropyl)carbonyl]benzoate

Refernces

• 1、 -. "DIPHENYL SUBSTITUTED ALKANES". Page/Page column 25. . Retrieved 2008/06/13.