10.1016/j.jcat.2017.07.017
The research investigates the synthesis, characterization, and photocatalytic properties of neodymium (Nd)-modified titanium dioxide (TiO2) nanoparticles prepared via the hydrothermal method. The study aims to enhance the visible light photocatalytic activity of TiO2 by doping it with Nd in the range of 0.1 to 1.0 mol%. The photocatalysts were characterized using various techniques, including diffuse reflectance spectroscopy (DRS), scanning electron microscopy (SEM), X-ray fluorescence (EDX), Brunauer–Emmett–Teller (BET) method, X-ray powder diffraction analysis (XRD), X-ray photoelectron spectroscopy (XPS), and photoluminescence spectroscopy (PL). The results showed that the Nd-modified TiO2 exhibited high photocatalytic activity under visible light, with the highest activity observed for the sample modified with 0.1 mol% Nd3+. This sample had a surface area of 124 m2/g and an average crystal size of 10.9 nm. The study also explored the excitation mechanism under visible light and concluded that the up-conversion process was not responsible for the degradation of phenol under visible light irradiation. The enhanced photocatalytic activity was attributed to the increased adsorption sites, BET surface area, decreased crystallite size, and prevention of electron-hole recombination.