O-Benzyllinalool

Base Information

• Chemical Name: O-Benzyllinalool
• CAS No.: 77611-58-6
• Molecular Formula: C17H24O
• Molecular Weight: 244.37
• Mol file: 77611-58-6.mol

Synonyms:[[(1-Vinyl-1,5-dimethyl-4-hexenyl)oxy]methyl]benzene;3,7-Dimethyl-3-(benzyloxy)-1,6-octadiene;O-Benzyllinalool

Chemical Property of O-Benzyllinalool

Chemical Property:

• Boiling Point: 101 °C(Press: 0.2 Torr)
• PSA: 9.23000
• Density: 0.919±0.06 g/cm3(Predicted)
• LogP: 4.89430

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of O-Benzyllinalool

There total 2 articles about O-Benzyllinalool which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

3,7-dimethylocta-1,6-dien-3-ol (78-70-6) + benzyl bromide (100-39-0) → 6-benzyloxy-2,6-dimethyl-2,7-octadiene (77611-58-6)

Guidance literature:

With tetra-(n-butyl)ammonium iodide; sodium hydride; In tetrahydrofuran; at 23 ℃; for 4h;

DOI:10.1021/ol051277c

Reference yield:

→ 6-benzyloxy-2,6-dimethyl-2,7-octadiene (77611-58-6)

Guidance literature:

With Lindlar's catalyst; lead containing palladium; Petroleum ether; Hydrogenation;

Reference yield: 5.0%

6-benzyloxy-2,6-dimethyl-2,7-octadiene (77611-58-6) → cis-4-(1-benzyloxy-1-methyl-ethyl)-1-methyl-bicyclo[3.1.0]hexane

Guidance literature:

With [(PPP)PtMe]BF₄; bis(trifluoromethanesulfonyl)amide; acetone; benzhydrylidene(methyl)amine; In nitromethane-d3; at 23 ℃; for 5h;

DOI:10.1021/ol051277c

upstream raw materials:

3,7-dimethylocta-1,6-dien-3-ol

benzyl bromide

Downstream raw materials:

4-Benzyloxy-4,8-dimethyl-non-7-enenitrile

Refernces