Trinaphthalen-1-ylstibane

Base Information

• Chemical Name: Trinaphthalen-1-ylstibane
• CAS No.: 27309-70-2
• Molecular Formula: C30H21Sb
• Molecular Weight: 503.247
• DSSTox Substance ID: DTXSID30407386
• Mol file: 27309-70-2.mol

Synonyms:Trinaphthalen-1-ylstibane;27309-70-2;TRIS(1-NAPHTHYL)ANTIMONY;trinaphthylstibine;Tri(naphthalen-1-yl)stibane;ANTIMONY TRI-A-NAPHTHYL;DTXSID30407386;AKOS024432928;NS00121494

Chemical Property of Trinaphthalen-1-ylstibane

Chemical Property:

• Melting Point: 218 °C
• PSA: 0.00000
• LogP: 8.25750
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 3
• Exact Mass: 502.06814
• Heavy Atom Count: 31
• Complexity: 504

Purity/Quality:

99% ^*data from raw suppliers

TRIS(1-NAPHTHYL)ANTIMONY Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C2C(=C1)C=CC=C2[Sb](C3=CC=CC4=CC=CC=C43)C5=CC=CC6=CC=CC=C65

Technology Process of Trinaphthalen-1-ylstibane

There total 7 articles about Trinaphthalen-1-ylstibane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.6%

antimony(III) chloride (10025-91-9) → tris(1-naphthyl)stilbane (27309-70-2)

Guidance literature:

In diethyl ether; Grignard synthesis, hydrolyzing; ppt. extg. with ether, evapn.;

Reference yield: 17.0%

1-Bromonaphthalene (90-11-9) + antimony(III) chloride (10025-91-9) → tris(1-naphthyl)stilbane (27309-70-2)

Guidance literature:

With lithium;

Reference yield:

naphthalen-1-yl-lithium (14474-59-0) → tris(1-naphthyl)stilbane (27309-70-2)

Guidance literature:

With diethyl ether; antimony(III) chloride; benzene;

upstream raw materials:

naphthalen-1-yl-lithium

1-naphthylmagnesiumbromide

antimony(III) chloride

1-Bromonaphthalene

Downstream raw materials:

1,1'-bisnaphthalene

4-(naphthalen-1-yl)but-3-en-2-one

4-(1-naphthyl)-2-butanone

tellurium