4-DECYL-2-IODOBENZENAMINE

Base Information

• Chemical Name: 4-DECYL-2-IODOBENZENAMINE
• CAS No.: 315716-39-3
• Molecular Formula: C16H26IN
• Molecular Weight: 359.294
• Mol file: 315716-39-3.mol

Synonyms:4-DECYL-2-IODOBENZENAMINE;4-N-DECYL-2-IODOANILINE

Chemical Property of 4-DECYL-2-IODOBENZENAMINE

Chemical Property:

• Melting Point: 44 - 46 °C (aq. ethanol)
• Boiling Point: 399.5±35.0 °C(Predicted)
• PKA: 2.89±0.10(Predicted)
• PSA: 26.02000
• Density: 1.289±0.06 g/cm3(Predicted)
• LogP: 6.13780

Purity/Quality:

4-DECYL-2-IODOBENZENAMINE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-DECYL-2-IODOBENZENAMINE

There total 1 articles about 4-DECYL-2-IODOBENZENAMINE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

4-n-decylaniline (37529-30-9) → 4-Decyl-2-iodoaniline (315716-39-3)

Guidance literature:

With calcium carbonate; benzyl triethylammonium dichloroiodate; In methanol; dichloromethane; at 20 ℃; for 3h;

DOI:10.1002/1521-3765(20000602)6:11<2044::AID-CHEM2044>3.0.CO;2-Y

Reference yield: 96.0%

diethylamine (109-89-7) + 4-Decyl-2-iodoaniline (315716-39-3) → N,N-Diethyl-N'-(4-decyl-2-iodophenyl)triazene (191231-74-0)

Guidance literature:

4-Decyl-2-iodoaniline; With hydrogenchloride; sodium nitrite; In tetrahydrofuran; diethyl ether; acetonitrile; at -5 - 0 ℃; for 0.5h;

diethylamine; With potassium carbonate; In tetrahydrofuran; diethyl ether; acetonitrile; for 0.5h; Further stages.;

DOI:10.1002/1521-3765(20000602)6:11<2044::AID-CHEM2044>3.0.CO;2-Y

Reference yield:

4-Decyl-2-iodoaniline (315716-39-3) → N,N-Diethyl-N'-[4-decyl-2-(triisopropylsilylethynyl)phenyl]triazene (315716-41-7)

Guidance literature:

Multi-step reaction with 2 steps

1.1: aq. HCl; NaNO₂ / diethyl ether; tetrahydrofuran; acetonitrile / 0.5 h / -5 - 0 °C

1.2: 96 percent / aq. K₂CO₃ / diethyl ether; tetrahydrofuran; acetonitrile / 0.5 h

2.1: 96 percent / CuI; NEt₃ / [PdCl₂(PPh₃)2] / 60 °C

With hydrogenchloride; copper(l) iodide; triethylamine; sodium nitrite; bis-triphenylphosphine-palladium(II) chloride; In tetrahydrofuran; diethyl ether; acetonitrile; 1.1: Diazotization / 1.2: Addition / 2.1: Cross-coupling reaction;

DOI:10.1002/1521-3765(20000602)6:11<2044::AID-CHEM2044>3.0.CO;2-Y

upstream raw materials:

4-n-decylaniline

Downstream raw materials:

N,N-Diethyl-N'-(4-decyl-2-iodophenyl)triazene

N,N-Diethyl-N'-[4-decyl-2-(triisopropylsilylethynyl)phenyl]triazene

4-Decyl-2-[(triisopropylsilyl)ethynyl]-1-[4-(trimethylsilyl)-1,3-butadiynyl]benzene

4-Decyl-1-iodo-2-[(triisopropylsilyl)ethynyl]benzene

Refernces

• 1、 Haley, Michael M.,Brand, Stephen C.,Pak, Joshua J.. "Carbon Networks Based on Dehydrobenoannulenes: Synthesis of Graphdiyne Substructures". . p. 835 - 838. Retrieved 2007/10/03.