2,3-Epoxypropyl nitrate

Base Information

• Chemical Name: 2,3-Epoxypropyl nitrate
• CAS No.: 6659-62-7
• Molecular Formula: C3H5 N O4
• Molecular Weight: 119.077
• Hs Code.: 2920909090
• European Community (EC) Number: 229-698-7
• NSC Number: 137875
• DSSTox Substance ID: DTXSID20950492
• Mol file: 6659-62-7.mol

Synonyms:glycidyl nitrate

Chemical Property of 2,3-Epoxypropyl nitrate

Chemical Property:

• Vapor Pressure: 1.26mmHg at 25°C
• Refractive Index: 1.4940 (estimate)
• Boiling Point: 179.7°C at 760 mmHg
• Flash Point: 101.5°C
• PSA: 67.58000
• Density: 1.409g/cm³
• LogP: 0.11670
• XLogP3: 0.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 119.02185764
• Heavy Atom Count: 8
• Complexity: 97.9

Purity/Quality:

99% ^*data from raw suppliers

2,3-EPOXYPROPYL NITRATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1C(O1)CO[N+](=O)[O-]

Technology Process of 2,3-Epoxypropyl nitrate

There total 9 articles about 2,3-Epoxypropyl nitrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

glycidyl p-toluenesulfonate (118712-54-2,6746-81-2) → 1,2-epoxy-3-nitratopropane (6659-62-7,27814-48-8)

Guidance literature:

With sodium nitrate; tetrabutylammonium nitrate; In acetonitrile; at 85 ℃; for 6h;

DOI:10.1021/op200066e

Reference yield: 30.0%

epichlorohydrin (106-89-8,24969-06-0,13403-37-7) → 1,2-epoxy-3-nitratopropane (6659-62-7,27814-48-8)

Guidance literature:

epichlorohydrin; With nitric acid; potassium nitrate; at 8 - 12 ℃; for 3h;

With sodium hydroxide; In water; at 5 ℃; for 3h;

DOI:10.1039/c5ra16476a

Reference yield:

glycerol (56-81-5,25618-55-7,64333-26-2,8013-25-0) → 1,3-bis(nitrooxy)propan-2-ol (623-87-0) + glyceryl 1,2-dinitrate (621-65-8) + glycerin trinitrate (55-63-0,9010-02-0) + 1,2-epoxy-3-nitratopropane (6659-62-7,27814-48-8)

Guidance literature:

glycerol; With nitric acid; at 22 ℃; for 0.141833h;

With sodium hydroxide; In water; at 32 ℃; for 0.018h; Temperature; Time; Concentration;

upstream raw materials:

epiiodohydrin

nitric acid-(3-chloro-2-hydroxy-propyl ester)

1,3-bis(nitrooxy)propan-2-ol

glyceryl 1,2-dinitrate

Refernces

• 1、 Shee, Sujit Kumar,Reddy, Sreekantha T.,Athar, Javaid,Sikder, Arun Kanti,Talawar,Banerjee, Shaibal,Khan, Md Abdul Shafeeuulla. "Probing the compatibility of energetic binder poly-glycidyl nitrate with energetic plasticizers: Thermal, rheological and DFT studies". . p. 101297 - 101308. Retrieved 2015/12/08.
• 2、 -. "Process for making stable cured poly(glycidyl nitrate) and energetic compositions comprising same". . . Retrieved 2008/06/13.