ethyl cis-4-hexenoate

Base Information

• Chemical Name: ethyl cis-4-hexenoate
• CAS No.: 34495-73-3
• Molecular Formula: C8H14O2
• Molecular Weight: 142.198
• Hs Code.: 2916190090
• Mol file: 34495-73-3.mol

Synonyms:ethyl cis-4-hexenoate

Chemical Property of ethyl cis-4-hexenoate

Chemical Property:

• PSA: 26.30000
• LogP: 1.90580

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of ethyl cis-4-hexenoate

There total 7 articles about ethyl cis-4-hexenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

(Z)-diethyl (but-2-en-1-yl)malonate (84200-40-8) → (Z)-hex-4-enoic acid methyl ester (34495-73-3)

Guidance literature:

With sodium chloride; In water; dimethyl sulfoxide; at 180 ℃;

DOI:10.1016/0040-4039(81)80041-X

Reference yield: 70.0%

(Z)-1-propenyl bromide (590-13-6) + ethyl acrylate (140-88-5,9003-32-1) → (Z)-hex-4-enoic acid methyl ester (34495-73-3)

Guidance literature:

With pyridine; nickel dichloride; zinc; In tetrahydrofuran; at 60 ℃; for 4h;

DOI:10.1016/S0040-4039(01)80283-5

Reference yield:

(Z)-2-Butene (590-18-1) + diethyl mercuribis(diazoacetate) (20363-85-3) → (Z)-hex-4-enoic acid methyl ester (34495-73-3)

Guidance literature:

Irradiation;

DOI:10.1021/ja00825a007

upstream raw materials:

(Z)-2-Butene

diethyl mercuribis(diazoacetate)

(Z)-1-propenyl bromide

ethyl acrylate

Downstream raw materials:

(Z)-4-hexenol

cis-hex-4-enal

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