CIS-1-BROMO-1-PROPENE

Base Information

• Chemical Name: CIS-1-BROMO-1-PROPENE
• CAS No.: 590-13-6
• Molecular Formula: C3H5 Br
• Molecular Weight: 120.977
• Mol file: 590-13-6.mol

Synonyms:1-Propene,1-bromo-, (Z)-; Propene, 1-bromo-, (Z)- (8CI); Propene, 1-bromo-, cis- (6CI);(Z)-1-Bromo-1-propene; (Z)-1-Bromopropene; (Z)-1-Propenyl bromide;cis-1-Bromo-1-propene; cis-1-Bromopropene; cis-1-Propenyl bromide

Chemical Property of CIS-1-BROMO-1-PROPENE

Chemical Property:

• Vapor Pressure: 219mmHg at 25°C
• Melting Point: -113°C
• Refractive Index: n20/D 1.4545(lit.)
• Boiling Point: 58.8°Cat760mmHg
• Flash Point: °C
• PSA: 0.00000
• Density: 1.425g/cm³
• LogP: 1.91490
• Sensitive.: Light Sensitive

Purity/Quality:

98%,99%, ^*data from raw suppliers

cis-1-Bromo-1-propene 97% ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,Xi
• Hazard Codes: F,Xi
• Statements: 11-36/37/38
• Safety Statements: 16-26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of CIS-1-BROMO-1-PROPENE

There total 10 articles about CIS-1-BROMO-1-PROPENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,3-dibromobutanoic acid (600-30-6) → (Z)-1-propenyl bromide (590-13-6) + trans-2-propenyl bromide (590-15-8)

Guidance literature:

With sodium hydrogencarbonate; N,N-dimethyl-formamide; at 70 ℃;

DOI:10.1021/jo01092a612

Reference yield:

hydrogen bromide (10035-10-6,12258-64-9) + prop-1-yne (74-99-7) → (Z)-1-propenyl bromide (590-13-6) + trans-2-propenyl bromide (590-15-8)

Guidance literature:

Addition bei UV-Licht in fluessiger Phase und in der Gasphase bei Raumtemperatur_.Irradiation;

DOI:10.1021/ja01555a028

Reference yield:

ethanol (64-17-5) + 1,2-Dibromopropane (78-75-1) + sodium phenoxide (139-02-6) → (Z)-1-propenyl bromide (590-13-6) + trans-2-propenyl bromide (590-15-8) + 2-bromoprop-1-ene (557-93-7)

Guidance literature:

DOI:10.1021/ja01119a066

upstream raw materials:

pyridine

erythro-2,3-dibromobutanoic acid

ethanol

1,2-Dibromopropane

Downstream raw materials:

1-phenylpropene

(Z)-propene-1-d1

trans-2-propenyl bromide

hepta-2c,5c-dien-4-one

Refernces

• 1、 Norris. "-". . p. 1579. Retrieved 1959.
• 2、 Matveeva,Erin,Kurz. "Synthesis of the Substituted Z-1-Bromo-1-alkenes and Arylacetylenes from 2,3-Dibromocarboxylic Acids". . p. 1065 - 1067. Retrieved 2007/10/03.