2-Oxo-3-(phenyliodonio)-1,2-dihydro-4-quinolinolate

Base Information

• Chemical Name: 2-Oxo-3-(phenyliodonio)-1,2-dihydro-4-quinolinolate
• CAS No.: 86795-52-0
• Molecular Formula: C₁₅H₁₀INO₂
• Molecular Weight: 0
• NSC Number: 370850,355179
• DSSTox Substance ID: DTXSID101007082,DTXSID50988607
• Mol file: 86795-52-0.mol

Synonyms:86795-52-0;2-oxo-3-(phenyliodonio)-1,2-dihydro-4-quinolinolate;68903-67-3;3-(phenyl-lambda3-iodanylidene)-1H-quinoline-2,4-dione;4-oxo-3-phenyliodonio-1H-quinolin-2-olate;DTXSID50988607;DTXSID101007082;HMS1529C08;CCG-43121;NSC355179;NSC370850;NSC-355179;NSC-370850;4-Hydroxy-3-(phenyliodaniumyl)quinolin-2-olate;AE-406/41055832;SR-01000633067-1;2-Hydroxy-3-(phenyl-lambda~3~-iodanylidene)quinolin-4(3H)-one

Chemical Property of 2-Oxo-3-(phenyliodonio)-1,2-dihydro-4-quinolinolate

Chemical Property:

• XLogP3: 2.9
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 362.97563
• Heavy Atom Count: 19
• Complexity: 412

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)I=C2C(=O)C3=CC=CC=C3NC2=O

Technology Process of 2-Oxo-3-(phenyliodonio)-1,2-dihydro-4-quinolinolate

There total 2 articles about 2-Oxo-3-(phenyliodonio)-1,2-dihydro-4-quinolinolate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(4-Hydroxy-2-oxo-1,2-dihydrochinolin-3-yl)-phenyliodonium methylsulfat → 2-Oxo-3-phenyliodonium-1,2-dihydrochinolin-4-olat (86795-52-0)

Guidance literature:

With weak base; Product distribution;

DOI:10.1007/BF00798414

Reference yield:

→ (2,4-Dihydroxy-quinolin-3-yl)-phenyl-iodonium (86795-52-0)

Guidance literature:

Chinolonderiv. 1b, (Diacetoxyiod)-benzol 2a;

Reference yield: 97.0%

2-Oxo-3-phenyliodonium-1,2-dihydrochinolin-4-olat (86795-52-0) → 3-Chlor-4-hydroxy-chinolin-2(1H)-on (14933-25-6)

Guidance literature:

With hydrogenchloride; In ethanol; at 80 ℃;

DOI:10.1007/BF00798414

Downstream raw materials:

3,4-Dihydroxy-chinolin-2(1H)-on

4-hydroxy-3-methoxy-2(1H)-quinolinone

4-Hydroxy-2-quinolone

4-hydroxy-3-(phenylthio)quinolin-2(1H)-one