Carbonyl[5,10,15,20-tetrakis(2,3,4,5,6-pentafluorophenyl)-21H,23H-porphinato]rutheniuM(II), Min. 98%

Base Information

• Chemical Name: Carbonyl[5,10,15,20-tetrakis(2,3,4,5,6-pentafluorophenyl)-21H,23H-porphinato]rutheniuM(II), Min. 98%
• CAS No.: 171899-61-9
• Molecular Formula: C₄₅H₈F₂₀N₄ORu
• Molecular Weight: 1101.62
• Mol file: 171899-61-9.mol

Synonyms:Carbonyl[5,10,15,20-tetrakis(2,3,4,5,6-pentafluorophenyl)-21H,23H-porphinato]rutheniuM(II), Min. 98%

Chemical Property of Carbonyl[5,10,15,20-tetrakis(2,3,4,5,6-pentafluorophenyl)-21H,23H-porphinato]rutheniuM(II), Min. 98%

Chemical Property:

Purity/Quality:

97% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Carbonyl[5,10,15,20-tetrakis(2,3,4,5,6-pentafluorophenyl)-21H,23H-porphinato]rutheniuM(II), Min. 98%

There total 2 articles about Carbonyl[5,10,15,20-tetrakis(2,3,4,5,6-pentafluorophenyl)-21H,23H-porphinato]rutheniuM(II), Min. 98% which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

dodecacarbonyl-triangulo-triruthenium (15243-33-1) + tetrakis(pentafluorophenyl)porphyrin (25440-14-6) → carbonyl(5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato)ruthenium(II) (171899-61-9)

Guidance literature:

In 1,2,4-Trichlorobenzene; at 195 - 200 ℃; Inert atmosphere;

DOI:10.1016/j.tetlet.2011.05.081

Reference yield: 73.0%

dodecacarbonyl-triangulo-triruthenium (15243-33-1) + 5,10,15,20-tetrakis(pentafluorophenyl)porphyrin → carbonyl(5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato)ruthenium(II) (171899-61-9)

Guidance literature:

In 1,2-dichloro-benzene; ligand and Ru complex refluxed in 1,2-dichlorobenzene under Ar, Ru complex added, reacted for 12 h; evapd. (vac.), chromd. (silica gel, toluene), solvent-removed;

DOI:10.1021/ic0520566

Reference yield: 95.0%

carbonyl(5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato)ruthenium(II) (171899-61-9) + diazodiphenylmethane (908093-98-1) → [((NCCHCHCC(C6F5))4)Ru(C(C6H5)2)]

Guidance literature:

In dichloromethane; soln. of Ph2CN2 in CH2Cl2 was added by syringe pump to soln. of Ru complex in CH2Cl2 for 8 h at room temp.; soln. was stirred for 2 h; evacuated (vac.); chromd. (silica gel, CH2Cl2/hexane, 1/2); elem. anal.;

DOI:10.1021/om034128b

upstream raw materials:

dodecacarbonyl-triangulo-triruthenium

tetrakis(pentafluorophenyl)porphyrin

Downstream raw materials:

dichloro(5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato)ruthenium(IV)