RUTHENIUM CARBONYL

Base Information

• Chemical Name: RUTHENIUM CARBONYL
• CAS No.: 15243-33-1
• Molecular Formula: C12O12Ru3
• Molecular Weight: 639.335
• Hs Code.: 28439000
• Mol file: 15243-33-1.mol

Synonyms:Rutheniumcarbonyl (Ru3(CO)12) (6CI,7CI);Dodecacarbonyl-triangulo-triruthenium;Dodecacarbonyltriruthenium;Triangulo-Triruthenium dodecacarbonyl;Trirutheniumdodecacarbonyl;Triruthenium dodecacarbonyl [Ru3(CO)12];cyclo-Tris(tetracarbonylruthenium)(3Ru-Ru);

Chemical Property of RUTHENIUM CARBONYL

Chemical Property:

• Appearance/Colour: Orange crystals
• Melting Point: 150 °C
• PSA: 0.00000
• LogP: -2.49600
• Storage Temp.: Inert atmosphere,Room Temperature
• Solubility.: Sparingly soluble in hydrocarbons (e.g. hexane, cyclohexane, ben
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 12
• Rotatable Bond Count: 0
• Exact Mass: 642.65431
• Heavy Atom Count: 27
• Complexity: 10

Purity/Quality:

47%, ^*data from raw suppliers

Triruthenium Dodecacarbonyl ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F, Xn
• Hazard Codes: F,Xn
• Statements: 11-20-2017/11/20
• Safety Statements: 24/25

MSDS Files:

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[Ru].[Ru].[Ru]
• Uses: A H-transfer catalyst. It is used in carbonylation catalysis of the allylic amination of unactivated olefins by nitroarenes, reductive carbonylation of mononitro aromatic compounds to carbamates, and as a catalyst for cycloaddition reactions. It is employed as a precursor for the synthesis of Ru nanoparticles. Catalyst used in the intermolecular [3+2+1] cycloaddition of alpha,beta-unsaturated ketones with silylacetylenes and carbon monoxide, to produce alpha-pyrones. Catalyzes the coupling of silanes with thiols, alcohols and amines with high turnover number (TON) and high turnover frequency (TOF).

Technology Process of RUTHENIUM CARBONYL

There total 366 articles about RUTHENIUM CARBONYL which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

H3Ru3(μ3-methoxymethylidyne)(carbonyl)9 (71562-47-5) → dodecacarbonyl-triangulo-triruthenium (15243-33-1) + ruthenium pentacarbonyl (16406-48-7) + Dimethyl ether (115-10-6,157621-61-9)

Guidance literature:

With carbon monoxide; hydrogen; In toluene; an autoclave containing a soln. of Ru3-cluster in toluene was pressurized to 500 psig with 1:1 CO-H2 and was heated at 130°C for 23 h; cooled, gases were vented through U-trap (liq. N2), condensate was shown to be Me2O and Ru(CO)5 by mass spectrometry, toluene soln. was filtered (ppt. - Ru3(CO)12 identified by IR data), filtrate evapd., residue chromd. on SiO2 to give addnl. Ru3(CO)12;

DOI:10.1021/om00074a003

Reference yield: 88.0%

Ru3(CO)10H(OCC6H4N(CH3)2) (140111-19-9) → dodecacarbonyl-triangulo-triruthenium (15243-33-1) + 4-dimethylamino-benzaldehyde (100-10-7)

Guidance literature:

With CO; In benzene; High Pressure; heating (3 bar CO, 90 min, 80°C); chromy. (hexane);

Reference yield: 73.0%

decacarbonyl-μ-benzylamido-μ-hydrido-triangulo-triruthenium → dodecacarbonyl-triangulo-triruthenium (15243-33-1) + benzylamine (100-46-9)

Guidance literature:

With carbon monoxide; In hexane; High Pressure; heating in autoclave (140°C, 130 bar CO, 16 h), cooling ro room temp.;

upstream raw materials:

ruthenium trichloride hydrate

carbon monoxide

ruthenium tetracarbonyl

ruthenium(III) chloride trihydrate

Downstream raw materials:

Ru3(CO)10(μ-bis(diphenylphosphino)methane)

ruthenium

carbon monoxide

tricarbonylbis(triphenylphosphine)ruthenium⁽⁰⁾

Refernces

Deoxygenation Reactions of ortho-Nitrostyrenes with Carbon Monoxide Catalysed by Metal Carbonyls: a New Route to Indoles

10.1039/c39860000784

The research explores a new route to synthesizing indoles through the deoxygenation of ortho-nitrostyrenes using carbon monoxide and metal carbonyl catalysts. The purpose is to develop a more selective and efficient method for constructing the indole nucleus under non-acidic conditions, which is of significant academic and industrial interest. Key chemicals used include Fe(CO)5, Ru3(CO)12, and Rh6(CO)16 as catalysts, along with various ortho-nitrostyrene substrates prepared via a modified Wittig reaction. The study found that Fe(CO)5 was the most selective catalyst, yielding primarily indoles with some side products like amines and quinolones. The method offers advantages over traditional deoxygenation methods, such as better selectivity and a simpler work-up procedure. The research also isolated a non-catalytically active rhodium complex during the synthesis, providing insights into the catalytic mechanism.

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