L-Valine, 3-Methyl-N-[[[(1R,2R)-2-(4-penten-1-yl)cyclopropyl]oxy]carbonyl]-

Base Information

Chemical Name:L-Valine, 3-Methyl-N-[[[(1R,2R)-2-(4-penten-1-yl)cyclopropyl]oxy]carbonyl]-
CAS No.:1026200-27-0
Molecular Formula:C15H25NO4
Molecular Weight:283.368
Hs Code.:
Mol file:1026200-27-0.mol

Synonyms:L-Valine, 3-Methyl-N-[[[(1R,2R)-2-(4-penten-1-yl)cyclopropyl]oxy]carbonyl]-;(S)-3,3-dimethyl-2-((((1R,2R)-2-(pent-4-en-1-yl)cyclopropoxy)carbonyl)amino)butanoic acid

Suppliers and Price of L-Valine, 3-Methyl-N-[[[(1R,2R)-2-(4-penten-1-yl)cyclopropyl]oxy]carbonyl]-

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 8 raw suppliers

Chemical Property of L-Valine, 3-Methyl-N-[[[(1R,2R)-2-(4-penten-1-yl)cyclopropyl]oxy]carbonyl]-

Chemical Property:

PSA：75.63000
LogP:3.34760

Purity/Quality:: 98% Min ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of L-Valine, 3-Methyl-N-[[[(1R,2R)-2-(4-penten-1-yl)cyclopropyl]oxy]carbonyl]-

There total 10 articles about L-Valine, 3-Methyl-N-[[[(1R,2R)-2-(4-penten-1-yl)cyclopropyl]oxy]carbonyl]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 1026200-25-8
methyl 3-methyl-N-({[(1R,2R)-2-pent-4-en-1-ylcyclopropyl]oxy}carbonyl)-L-valinate

: 1026200-27-0
3-methyl-N-({[(1R,2R)-2-pent-4-en-1-ylcyclopropyl]oxy}carbonyl)-L-valine

Guidance literature:: methyl 3-methyl-N-({[(1R,2R)-2-pent-4-en-1-ylcyclopropyl]oxy}carbonyl)-L-valinate; With lithium hydroxide monohydrate; water; In methanol; at 60 ℃; for 4h;

With hydrogenchloride; In water; ethyl acetate;

Reference yield:

: trimethyl{[(trans)-2-pent-4-en-1-ylcyclopropyl]oxy}silane

: 1026200-27-0
3-methyl-N-({[(1R,2R)-2-pent-4-en-1-ylcyclopropyl]oxy}carbonyl)-L-valine

Guidance literature:: Multi-step reaction with 3 steps

1: pyridine; tetrabutyl ammonium fluoride / tetrahydrofuran; toluene / 0 - 20 °C / Inert atmosphere

2: dmap / toluene / 6 h / Inert atmosphere; Reflux

3: lithium hydroxide monohydrate; water / methanol / 4 h / 60 °C / Inert atmosphere

With pyridine; dmap; lithium hydroxide monohydrate; tetrabutyl ammonium fluoride; water; In tetrahydrofuran; methanol; toluene;
DOI:10.1021/ml300017p

Reference yield:

: 1384277-05-7
trans 2-(pent-4-en-1-yl)cyclopropanol

: 1026200-27-0
3-methyl-N-({[(1R,2R)-2-pent-4-en-1-ylcyclopropyl]oxy}carbonyl)-L-valine

Guidance literature:: Multi-step reaction with 2 steps

1: dmap / toluene / 6 h / Inert atmosphere; Reflux

2: lithium hydroxide monohydrate; water / methanol / 4 h / 60 °C / Inert atmosphere

With dmap; lithium hydroxide monohydrate; water; In methanol; toluene;
DOI:10.1021/ml300017p