ethyl 2-(4-(trifluoromethylsulfonyloxy)cyclohex-3-enyl)acetate

Base Information

Chemical Name:ethyl 2-(4-(trifluoromethylsulfonyloxy)cyclohex-3-enyl)acetate
CAS No.:1166829-72-6
Molecular Formula:C11H15F3O5S
Molecular Weight:316.298
Hs Code.:
Mol file:1166829-72-6.mol

Synonyms:ethyl 2-(4-(trifluoromethylsulfonyloxy)cyclohex-3-enyl)acetate

Suppliers and Price of ethyl 2-(4-(trifluoromethylsulfonyloxy)cyclohex-3-enyl)acetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 5 raw suppliers

Chemical Property of ethyl 2-(4-(trifluoromethylsulfonyloxy)cyclohex-3-enyl)acetate

Chemical Property:

PSA：78.05000
LogP:3.57060

Purity/Quality:: 98%min ^*data from raw suppliers

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Technology Process of ethyl 2-(4-(trifluoromethylsulfonyloxy)cyclohex-3-enyl)acetate

There total 4 articles about ethyl 2-(4-(trifluoromethylsulfonyloxy)cyclohex-3-enyl)acetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 358-23-6
trifluoromethylsulfonic anhydride

: 58012-34-3
ethyl 4-oxocyclohexaneacetate

: 1166829-72-6
ethyl 2-(4-(((trifluoromethyl)sulfonyl)oxy)cyclohex-3-en-1-yl)acetate

Guidance literature:: With 2,6-di-tert-butyl-4-methylpyridine; In dichloromethane; at 20 ℃; for 17h;
DOI:10.1021/jm301296t

Reference yield:

: 4746-97-8
cyclohexanedione monoethylene ketal

: 1166829-72-6
ethyl 2-(4-(((trifluoromethyl)sulfonyl)oxy)cyclohex-3-en-1-yl)acetate

Guidance literature:: Multi-step reaction with 4 steps

1.1: sodium hydride / tetrahydrofuran; mineral oil / 1 h / 0 °C

1.2: 0 - 20 °C

2.1: palladium on activated charcoal; hydrogen / methanol / 3 h / 20 °C

3.1: hydrogenchloride / water / 70 °C

4.1: lithium hexamethyldisilazane / tetrahydrofuran / 1 h / -78 °C

4.2: -78 - 20 °C / Inert atmosphere

With hydrogenchloride; palladium on activated charcoal; hydrogen; sodium hydride; lithium hexamethyldisilazane; In tetrahydrofuran; methanol; water; mineral oil;

Reference yield:

: 62141-26-8
ethyl 1,4-dioxaspiro[4.5]dec-8-ylacetate

: 1166829-72-6
ethyl 2-(4-(((trifluoromethyl)sulfonyl)oxy)cyclohex-3-en-1-yl)acetate

Guidance literature:: Multi-step reaction with 2 steps

1.1: hydrogenchloride / water / 70 °C

2.1: lithium hexamethyldisilazane / tetrahydrofuran / 1 h / -78 °C

2.2: -78 - 20 °C / Inert atmosphere

With hydrogenchloride; lithium hexamethyldisilazane; In tetrahydrofuran; water;