(4-iodophenyl)diphenyl-Phosphine

Base Information

• Chemical Name: (4-iodophenyl)diphenyl-Phosphine
• CAS No.: 440111-10-4
• Molecular Weight: 388.18
• Mol file: 440111-10-4.mol

Synonyms:(4-iodophenyl)diphenyl-Phosphine

Chemical Property of (4-iodophenyl)diphenyl-Phosphine

Chemical Property:

• Boiling Point: 412.6±28.0 °C(Predicted)
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature

Purity/Quality:

99% ^*data from raw suppliers

(4-Iodophenyl)diphenylphosphane ≥98% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (4-iodophenyl)diphenyl-Phosphine

There total 3 articles about (4-iodophenyl)diphenyl-Phosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

(4-bromophenyl)diphenylphosphane (734-59-8) → (4-iodophenyl)diphenylphosphine (440111-10-4)

Guidance literature:

(4-bromophenyl)diphenylphosphane; With n-butyllithium; In hexane; at -78 ℃; for 0.666667h; Inert atmosphere; Schlenk technique;

With iodine; In tetrahydrofuran; at -78 - 20 ℃; for 16h; Inert atmosphere; Schlenk technique;

DOI:10.1039/c2dt31507f

Reference yield: 45.0%

para-diiodobenzene (624-38-4,1032416-46-8) + diphenylphosphane (829-85-6) → 1,4-Bis(diphenylphosphino)benzene (1179-06-2) + (4-iodophenyl)diphenylphosphine (440111-10-4)

Guidance literature:

With 2-ethylbutanamide; palladium diacetate; at 70 - 80 ℃;

DOI:10.1016/S0022-328X(01)01371-7

Reference yield: 10.7%

iodobenzene (591-50-4) + chloro-diphenylphosphine (1079-66-9,74391-44-9) → (4-iodophenyl)diphenylphosphine (440111-10-4)

Guidance literature:

iodobenzene; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1h;

chloro-diphenylphosphine; In tetrahydrofuran; at -78 - 20 ℃;

DOI:10.1039/c3cc46903d

upstream raw materials:

para-diiodobenzene

diphenylphosphane

(4-bromophenyl)diphenylphosphane

iodobenzene

Downstream raw materials:

(4-(bromomethyl)benzyl)(4-iodophenyl)diphenylphosphonium bromide

Refernces

• 1、 Wen, Hui-Min,Wang, Jin-Yun,Hu, Ming-Qiang,Li, Bin,Chen, Zhong-Ning,Chen, Chang-Neng. "Photoswitchable electrochemical behaviour of a [FeFe] hydrogenase model with a dithienylethene derivative". . p. 11813 - 11819. Retrieved 2013/03/13.