IRON(II) PHTHALOCYANINE BIS(PYRIDINE)

Base Information

• Chemical Name: IRON(II) PHTHALOCYANINE BIS(PYRIDINE)
• CAS No.: 20219-84-5
• Molecular Formula: C32H16FeN8.2C5H5N
• Molecular Weight: 726.582
• Mol file: 20219-84-5.mol

Synonyms:IRON(II) PHTHALOCYANINE BIS(PYRIDINE);Iron(Ⅱ) phthalocyanine bis(pyridine) coMplex

Chemical Property of IRON(II) PHTHALOCYANINE BIS(PYRIDINE)

Chemical Property:

• PSA: 109.80000
• LogP: 3.62510

Purity/Quality:

98% ^*data from raw suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of IRON(II) PHTHALOCYANINE BIS(PYRIDINE)

There total 2 articles about IRON(II) PHTHALOCYANINE BIS(PYRIDINE) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

μ-oxo-bisphthalocyaninato(2-)ferrate(III) (74353-48-3) → bis(pyridine)phthalocyanatoiron(II) (20219-84-5) + Triphenylphosphine oxide (791-28-6)

Guidance literature:

With pyridine; triphenylphosphine; In pyridine; toluene; N2-atmosphere; molar ratio Fe-complex:PPh3=1:1, room temp., stirring (48 h, pptn.); filtration;

DOI:10.1039/c39830000549

Reference yield:

(μ-oxo)[(5,10,15,20-tetraphenylporphyrinato)chromium(III)][(phthalocyaninato)iron(III)]*2H2O → bis(pyridine)phthalocyanatoiron(II) (20219-84-5) + CrO(NC4H2C(C6H5))4(C5H5N) (94890-19-4)

Guidance literature:

With pyridine; O₂; In pyridine; soln. exposed to air; detected by UV-vis spectra;

Reference yield:

bis(pyridine)phthalocyanatoiron(II) (20219-84-5) → pyridine (110-86-1) + iron(II) phthalocyanine (132-16-1)

Guidance literature:

In neat (no solvent); heating above 225°C; X-ray powder diffraction;

DOI:10.1016/S0020-1693(02)01060-5

upstream raw materials:

μ-oxo-bisphthalocyaninato(2-)ferrate(III)

Downstream raw materials:

(phthalocyaninato)iron(II)

pyridine

iron(II) phthalocyanine

Refernces

• 1、 Liston, David J.,Kennedy, Brendan J.,Murray, Keith S.,West, Bruce O.. "Oxochromium compounds. 1. Synthesis and properties of μ-oxo chromium-iron porphyrin and phthalocyanine compounds". . p. 1561 - 1567. Retrieved 2008/10/08.