Xantphos Palladacycle Gen. 3

Base Information

• Chemical Name: Xantphos Palladacycle Gen. 3
• CAS No.: 1445085-97-1
• Molecular Formula: C₁₃H₁₃NO₃PdS*C₃₉H₃₂OP₂
• Molecular Weight: 948.367
• Mol file: 1445085-97-1.mol

Synonyms:Methanesulfonato[9,9-diMethyl-4,5-bis(diphenylphosphino)xanthene][2'-aMino-1,1'-biphenyl]palladiuM(II) dichloroMethane adduct, Min. 98%;Methanesulfonato[9,9-diMethyl-4,5-bis(diphenylphosphino)xanthene][2'-aMino-1,1'-biphenyl]palladium(II)

Chemical Property of Xantphos Palladacycle Gen. 3

Chemical Property:

• Storage Temp.: under inert gas (nitrogen or Argon) at 2–8 °C

Purity/Quality:

98% ^*data from raw suppliers

Methanesulfonato[9,9-dimethyl-4,5-bis(diphenylphosphino)xanthene][2'-amino-1,1'-biphenyl]palladium(II) dichloromethane adduct, min. 98% [Xantphos Palladacycle Gen. 3] ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Uses: Xantphos Pd G3 is used as a catalyst in many reactions. It is a third generation (G3) Buchwald precatalyst. XantPhos Pd G3 is an excellent reagent for palladium catalyzed cross-coupling reactions.

Technology Process of Xantphos Palladacycle Gen. 3

There total 3 articles about Xantphos Palladacycle Gen. 3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

(2'-amino-1,1'-biphenyl-2-yl)methanesulfonatopalladium(II) dimer (1435520-65-2) + 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene (161265-03-8) → C39H32OP2*C13H13NO3PdS (1445085-97-1)

Guidance literature:

In tetrahydrofuran; at 20 ℃;

DOI:10.1039/c2sc20903a

Reference yield:

2-phenylaniline (90-41-5) → C39H32OP2*C13H13NO3PdS (1445085-97-1)

Guidance literature:

Multi-step reaction with 3 steps

1: Isopropyl acetate / 20 °C

2: toluene / 65 °C

3: tetrahydrofuran / 20 °C

In tetrahydrofuran; Isopropyl acetate; toluene;

DOI:10.1039/c2sc20903a

Reference yield:

[1,1'-biphenyl]-2-aminium methanesulfonate (1445085-50-6) → C39H32OP2*C13H13NO3PdS (1445085-97-1)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene / 65 °C

2: tetrahydrofuran / 20 °C

In tetrahydrofuran; toluene;

DOI:10.1039/c2sc20903a

upstream raw materials:

(2'-amino-1,1'-biphenyl-2-yl)methanesulfonatopalladium(II) dimer

4,5-bis(diphenylphosphino)-9,9-dimethylxanthene

2-phenylaniline

[1,1'-biphenyl]-2-aminium methanesulfonate

Refernces