D-arabino-Heptononitrile, 2,6-anhydro-3,4-dideoxy-5,7-di-O-methyl- (9CI)

Base Information

Chemical Name:D-arabino-Heptononitrile, 2,6-anhydro-3,4-dideoxy-5,7-di-O-methyl- (9CI)
CAS No.:501101-19-5
Molecular Formula:C₉H₁₅NO₃
Molecular Weight:185.223
Hs Code.:
Mol file:501101-19-5.mol

Synonyms:D-arabino-Heptononitrile, 2,6-anhydro-3,4-dideoxy-5,7-di-O-methyl- (9CI)

Suppliers and Price of D-arabino-Heptononitrile, 2,6-anhydro-3,4-dideoxy-5,7-di-O-methyl- (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of D-arabino-Heptononitrile, 2,6-anhydro-3,4-dideoxy-5,7-di-O-methyl- (9CI)

Chemical Property:

PSA：51.48000
LogP:0.71898

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

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Technology Process of D-arabino-Heptononitrile, 2,6-anhydro-3,4-dideoxy-5,7-di-O-methyl- (9CI)

There total 1 articles about D-arabino-Heptononitrile, 2,6-anhydro-3,4-dideoxy-5,7-di-O-methyl- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 116431-54-0
2,3-dideoxy-α-D-erythro-hexopyranosyl cyanide

: 74-88-4
methyl iodide

: 501101-19-5
2,6-anhydro-3,4-dideoxy-5,7-di-O-methyl-D-arabino-heptonitrile

Guidance literature:: 2,3-dideoxy-α-D-erythro-hexopyranosyl cyanide; With sodium hydride; In N,N-dimethyl-formamide; at 0 ℃;

methyl iodide; In N,N-dimethyl-formamide; at 20 ℃; for 2h; Further stages.;
DOI:10.1021/jo026314h

Reference yield:

: 501101-19-5
2,6-anhydro-3,4-dideoxy-5,7-di-O-methyl-D-arabino-heptonitrile

: 326478-83-5
2,6-anhydro-1,3,4-trideoxy-1-[(diphenoxyphosphoryl)amino]-5,7-di-O-methyl-D-arabino-heptitol

Guidance literature:: Multi-step reaction with 2 steps

1: LiAlH₄ / tetrahydrofuran / 1 h / 20 °C

2: TEA / CH₂Cl₂ / 1.5 h / 20 °C

With lithium aluminium tetrahydride; TEA; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo026314h

Reference yield:

: 501101-19-5
2,6-anhydro-3,4-dideoxy-5,7-di-O-methyl-D-arabino-heptonitrile

: 2,7-anhydro-4,5,7-trideoxy-7-[(diphenoxyphosphoryl)amino]-1,3-di-O-methyl-β-D-threo-hept-2-ulofuranose

Guidance literature:: Multi-step reaction with 3 steps

1: LiAlH₄ / tetrahydrofuran / 1 h / 20 °C

2: TEA / CH₂Cl₂ / 1.5 h / 20 °C

3: 11 percent / I₂ / CH₂Cl₂ / 0.83 h / 20 °C / Irradiation

With lithium aluminium tetrahydride; TEA; iodine; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo026314h