2-(2-O,3-O,4-O,6-O-Tetraacetyl-β-D-glucopyranosyloxy)-5-acetyloxybenzoic acid benzyl ester

Base Information

Chemical Name:2-(2-O,3-O,4-O,6-O-Tetraacetyl-β-D-glucopyranosyloxy)-5-acetyloxybenzoic acid benzyl ester
CAS No.:17019-77-1
Molecular Formula:C30H32O14
Molecular Weight:616.57
Hs Code.:
Mol file:17019-77-1.mol

Synonyms:2-(2-O,3-O,4-O,6-O-Tetraacetyl-β-D-glucopyranosyloxy)-5-acetyloxybenzoic acid benzyl ester;Trichocarpin pentaacetate

Suppliers and Price of 2-(2-O,3-O,4-O,6-O-Tetraacetyl-β-D-glucopyranosyloxy)-5-acetyloxybenzoic acid benzyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 3 raw suppliers

Chemical Property of 2-(2-O,3-O,4-O,6-O-Tetraacetyl-β-D-glucopyranosyloxy)-5-acetyloxybenzoic acid benzyl ester

Chemical Property:

Purity/Quality:: 99% ^*data from raw suppliers

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Technology Process of 2-(2-O,3-O,4-O,6-O-Tetraacetyl-β-D-glucopyranosyloxy)-5-acetyloxybenzoic acid benzyl ester

There total 4 articles about 2-(2-O,3-O,4-O,6-O-Tetraacetyl-β-D-glucopyranosyloxy)-5-acetyloxybenzoic acid benzyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: benzyl 5-acetoxy-2-hydroxybenzoate

: 572-09-8
2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

: 17019-77-1
benzyl 2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyloxy)-5-acetoxybenzoate

Guidance literature:: With silver(l) oxide; In quinoline; at 20 ℃; for 1h;
DOI:10.1021/acs.jnatprod.0c00838

Reference yield:

: 100-39-0
benzyl bromide

: 17019-77-1
benzyl 2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyloxy)-5-acetoxybenzoate

Guidance literature:: Multi-step reaction with 3 steps

1: sodium hydrogencarbonate / N,N-dimethyl-formamide / 18 h / 20 °C

2: 24 h / 20 °C

3: silver(l) oxide / quinoline / 1 h / 20 °C

With sodium hydrogencarbonate; silver(l) oxide; In quinoline; N,N-dimethyl-formamide; 3: |Koenigs-Knorr Glycosidation;
DOI:10.1021/acs.jnatprod.0c00838

Reference yield:

: 490-79-9
2,5-dihydroxybenzoic acid.

: 17019-77-1
benzyl 2-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyloxy)-5-acetoxybenzoate

Guidance literature:: Multi-step reaction with 3 steps

1: sodium hydrogencarbonate / N,N-dimethyl-formamide / 18 h / 20 °C

2: 24 h / 20 °C

3: silver(l) oxide / quinoline / 1 h / 20 °C

With sodium hydrogencarbonate; silver(l) oxide; In quinoline; N,N-dimethyl-formamide; 3: |Koenigs-Knorr Glycosidation;
DOI:10.1021/acs.jnatprod.0c00838