3-Cyclohexene-1-carbonyl fluoride, 2-methoxy-, (1S-cis)- (9CI)

Base Information

Chemical Name:3-Cyclohexene-1-carbonyl fluoride, 2-methoxy-, (1S-cis)- (9CI)
CAS No.:159415-28-8
Molecular Formula:C8H11FO2
Molecular Weight:158.173
Hs Code.:
Mol file:159415-28-8.mol

Synonyms:3-Cyclohexene-1-carbonyl fluoride, 2-methoxy-, (1S-cis)- (9CI)

Suppliers and Price of 3-Cyclohexene-1-carbonyl fluoride, 2-methoxy-, (1S-cis)- (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 2 raw suppliers

Chemical Property of 3-Cyclohexene-1-carbonyl fluoride, 2-methoxy-, (1S-cis)- (9CI)

Chemical Property:

PSA：26.30000
LogP:1.46370

Purity/Quality:: 99%+ ^*data from raw suppliers

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Technology Process of 3-Cyclohexene-1-carbonyl fluoride, 2-methoxy-, (1S-cis)- (9CI)

There total 4 articles about 3-Cyclohexene-1-carbonyl fluoride, 2-methoxy-, (1S-cis)- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 158252-23-4
(1S,2R)-2-methoxy-3-cyclohexenyl-1-carboxylic acid

: 159415-28-8
2-methoxy-3-cyclohexenyl-1-carboxylic acid fluoride

Guidance literature:: With pyridine; trifluoro-[1,3,5]triazine; In dichloromethane; at -30 - -20 ℃; for 1h;
DOI:10.1080/00397919408019061

Reference yield:

: 158195-43-8
acetic acid (6S)-(10,10-dimethyl-3,3-dioxo-3λ⁶-thia-4-aza-tricyclo[5.2.1.0^1,5]decane-4-carbonyl)-(1R)-cyclohex-2-enyl ester

: 159415-28-8
2-methoxy-3-cyclohexenyl-1-carboxylic acid fluoride

Guidance literature:: Multi-step reaction with 3 steps

1: 99 percent / LiOH*H₂O / tetrahydrofuran; H₂O / Ambient temperature

2: 1.) KOH, Bu₄NHSO₄, 2.) H₂O / 1.) THF

3: 90 percent / cyanuric fluoride, pyridine / CH₂Cl₂ / -30 - -20 °C

With pyridine; potassium hydroxide; lithium hydroxide; trifluoro-[1,3,5]triazine; water; tetra(n-butyl)ammonium hydrogensulfate; In tetrahydrofuran; dichloromethane; water;
DOI:10.1021/jo951693i

Reference yield:

: 159517-29-0
(1S,2R)-2-hydroxy-3-cyclohexanecarboxylic acid

: 159415-28-8
2-methoxy-3-cyclohexenyl-1-carboxylic acid fluoride

Guidance literature:: Multi-step reaction with 2 steps

1: 1.) KOH, Bu₄NHSO₄, 2.) H₂O / 1.) THF

2: 90 percent / cyanuric fluoride, pyridine / CH₂Cl₂ / -30 - -20 °C

With pyridine; potassium hydroxide; trifluoro-[1,3,5]triazine; water; tetra(n-butyl)ammonium hydrogensulfate; In dichloromethane;
DOI:10.1021/jo951693i