N,N-bis(pyridin-2-ylMethyl)ethanaMine

Base Information

• Chemical Name: N,N-bis(pyridin-2-ylMethyl)ethanaMine
• CAS No.: 142723-81-7
• Molecular Formula: C14H17N3
• Molecular Weight: 227.309
• Mol file: 142723-81-7.mol

Synonyms:N,N-bis(pyridin-2-ylMethyl)ethanaMine

Chemical Property of N,N-bis(pyridin-2-ylMethyl)ethanaMine

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of N,N-bis(pyridin-2-ylMethyl)ethanaMine

There total 1 articles about N,N-bis(pyridin-2-ylMethyl)ethanaMine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2-chloromethylpyridine (4377-33-7) + ethylamine (75-04-7,85404-22-4) → N-ethyl-N,N-bis(2-pyridylmethyl)amine (142723-81-7)

Guidance literature:

In acetonitrile;

DOI:10.1002/ejic.201100953

Reference yield: 90.0%

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + N-ethyl-N,N-bis(2-pyridylmethyl)amine (142723-81-7) → cis,fac-[RuCl2(N,N-bis(2-pyridylmethyl)ethylamine)(PPh3)]*4H2O

Guidance literature:

In tetrahydrofuran; (N2); Schlenk technique; soln. of ligand and Ru complex in THF was refluxed for 1 h; cooled to room temp.; filtered; washed (hexane, ether); dried (vac.); elem. anal.;

DOI:10.1021/ic061126l

Reference yield: 47.0%

Tc(NO)Cl2(P(C6H5)3)2(HOCH3) + N-ethyl-N,N-bis(2-pyridylmethyl)amine (142723-81-7) → [Tc(NO)Cl(di(2-picolyl)(N-ethyl)amine)(PPh3)]Cl

Guidance literature:

In dichloromethane; ligand added to DCM soln. of Tc compd. (0.075:0.072 molar ratio), mixt. stirred overnight at room temp.; concd., washed (ether), evapd., dissolved (DCM), layered (MeOH, ether), crystd.;

DOI:10.1016/j.ica.2011.04.002

upstream raw materials:

2-chloromethylpyridine

ethylamine