(5-(tert-Butyl)-2-methoxyphenyl)boronic acid

Base Information

Chemical Name:(5-(tert-Butyl)-2-methoxyphenyl)boronic acid
CAS No.:128733-85-7
Molecular Formula:C11H17BO3
Molecular Weight:208.065
Hs Code.:2931900090
European Community (EC) Number:681-187-1
DSSTox Substance ID:DTXSID20563485
Nikkaji Number:J2.042.080D
Wikidata:Q69999988
Mol file:128733-85-7.mol

Synonyms:128733-85-7;(5-(tert-Butyl)-2-methoxyphenyl)boronic acid;5-tert-butyl-2-methoxyphenylboronic acid;(5-tert-butyl-2-methoxyphenyl)boronic acid;5-TERT-BUTYL-2-METHOXYBENZENEBORONIC ACID;5-t-Butyl-2-methoxyphenylboronic acid;Boronic acid, B-[5-(1,1-dimethylethyl)-2-methoxyphenyl]-;SCHEMBL1506563;DTXSID20563485;LXFOJKCQSAYVMF-UHFFFAOYSA-N;MFCD06201034;AKOS015837818;AB23099;AM90038;BS-20621;5-(tert-butyl)-2-methoxyphenylboronic acid;CS-0154916

Suppliers and Price of (5-(tert-Butyl)-2-methoxyphenyl)boronic acid

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
5-t-Butyl-2-methoxyphenylboronicacid
1g
$ 210.00

SynQuest Laboratories
5-(tert-Butyl)-2-methoxybenzeneboronic acid
250 mg
$ 48.00

SynQuest Laboratories
5-(tert-Butyl)-2-methoxybenzeneboronic acid
1 g
$ 125.00

Matrix Scientific
5-tert-Butyl-2-methoxyphenylboronic acid
5g
$ 542.00

Matrix Scientific
5-tert-Butyl-2-methoxyphenylboronic acid
10g
$ 900.00

Matrix Scientific
5-tert-Butyl-2-methoxyphenylboronic acid
25g
$ 1800.00

Crysdot
(5-(tert-Butyl)-2-methoxyphenyl)boronicacid 95+%
5g
$ 357.00

Chemenu
(5-(tert-Butyl)-2-methoxyphenyl)boronicacid 95%
25g
$ 1603.00

American Custom Chemicals Corporation
5-TERT-BUTYL-2-METHOXYBENZENEBORONIC ACID 95.00%
5G
$ 1350.00

American Custom Chemicals Corporation
5-TERT-BUTYL-2-METHOXYBENZENEBORONIC ACID 95.00%
1G
$ 590.00

Total 20 raw suppliers

Chemical Property of (5-(tert-Butyl)-2-methoxyphenyl)boronic acid

Chemical Property:

Vapor Pressure:1.11E-05mmHg at 25°C
Melting Point:103-106°C
Boiling Point:355.8°C at 760 mmHg
Flash Point:169°C
PSA：49.69000
Density:1.06g/cm³
LogP:0.67250
Storage Temp.:under inert gas (nitrogen or Argon) at 2-8°C
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:208.1270746
Heavy Atom Count:15
Complexity:201

Purity/Quality:

98%min ^*data from raw suppliers

5-t-Butyl-2-methoxyphenylboronicacid ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 36/37/38
Safety Statements: 26-36/37/39

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:B(C1=C(C=CC(=C1)C(C)(C)C)OC)(O)O

Technology Process of (5-(tert-Butyl)-2-methoxyphenyl)boronic acid

There total 6 articles about (5-(tert-Butyl)-2-methoxyphenyl)boronic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

: 5419-55-6
Triisopropyl borate

: 41280-65-3
2-bromo-4-tert-butylanisole

: 128733-85-7
(5-(tert-butyl)-2-methoxyphenyl)boronic acid

Guidance literature:: With n-butyllithium; In tetrahydrofuran; hexane; at -78 - 0 ℃; for 4.5h; Inert atmosphere;

Reference yield: 39.0%

: 75060-39-8
4-(tert-butyl)-2-iodo-1-methoxybenzene

: 128733-85-7
(5-(tert-butyl)-2-methoxyphenyl)boronic acid

Guidance literature:: 4-(tert-butyl)-2-iodo-1-methoxybenzene; With n-butyllithium; In tetrahydrofuran; hexane; at -78 ℃; for 0.0833333h; Inert atmosphere;

With Trimethyl borate; In tetrahydrofuran; diethyl ether; hexane; at -50 ℃; for 0.5h; Inert atmosphere;

With hydrogenchloride; In tetrahydrofuran; diethyl ether; hexane; water; at 20 ℃;
DOI:10.1246/bcsj.20110309

Reference yield:

: 5396-38-3
1-(tert-butyl)-4-methoxybenzene

: 128733-85-7
(5-(tert-butyl)-2-methoxyphenyl)boronic acid

Guidance literature:: Multi-step reaction with 2 steps

1.1: iodine; Selectfluor / acetonitrile / 4 h / 20 °C / Inert atmosphere

2.1: n-butyllithium / tetrahydrofuran; hexane / 0.08 h / -78 °C / Inert atmosphere

2.2: 0.5 h / -50 °C / Inert atmosphere

2.3: 20 °C

With n-butyllithium; iodine; Selectfluor; In tetrahydrofuran; hexane; acetonitrile;
DOI:10.1246/bcsj.20110309