(1α,6α)-7,7-Norcaranedicarbonitrile

Base Information

• Chemical Name: (1α,6α)-7,7-Norcaranedicarbonitrile
• CAS No.: 29782-28-3
• Molecular Formula: C₉H₁₀N₂
• Molecular Weight: 146.192
• Mol file: 29782-28-3.mol

Synonyms:(1α,6α)-7,7-Norcaranedicarbonitrile

Chemical Property of (1α,6α)-7,7-Norcaranedicarbonitrile

Chemical Property:

• PSA: 47.58000
• LogP: 1.83996

Purity/Quality:

95% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (1α,6α)-7,7-Norcaranedicarbonitrile

There total 2 articles about (1α,6α)-7,7-Norcaranedicarbonitrile which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

malononitrile (109-77-3) + cyclohexene (110-83-8) → bicyclo<4.1.0>heptane-7,7-dicarbonitrile (29782-28-3)

Guidance literature:

With sulfuryl dichloride; Dimethyldisulphide; sodium hydride; triethylamine; dimethyl sulfate; Yield given. Multistep reaction; 12) CH₂Cl₂, -50 deg, 2) THF, reflux, 15 h, 3) RT, 120 h then DMF, RT, 90 min;

DOI:10.1002/hlca.19940770502

Reference yield:

→ 7,7-Dicyanonorcaran (29782-28-3)

Guidance literature:

Bromdicyanomethan, Cyclohexen (1a);

DOI:10.1016/S0040-4020(01)92938-2

Reference yield: 6.3%

bicyclo<4.1.0>heptane-7,7-dicarbonitrile (29782-28-3) → 2-(cyclohex-2-enyl)malononitrile (6904-13-8,150921-95-2,150921-96-3)

Guidance literature:

With hydroxocobalamine hydrochloride; lithium perchlorate; ammonium chloride; zinc; In N,N-dimethyl-formamide; at 60 ℃; for 48h;

DOI:10.1002/hlca.19940770502

upstream raw materials:

malononitrile

cyclohexene

Downstream raw materials:

trans-(2-Chlor-cyclohexyl)-cyanessigsaeure

2-(cyclohex-2-enyl)malononitrile

Refernces