1,3,5-Tris(4'-carboxy[1,1'-biphenyl]-4-yl)benzene

Base Information

• Chemical Name: 1,3,5-Tris(4'-carboxy[1,1'-biphenyl]-4-yl)benzene
• CAS No.: 911818-75-2
• Molecular Formula: C45H30O6
• Molecular Weight: 666.73
• Mol file: 911818-75-2.mol

Synonyms:1,3,5-Tris(4'-carboxy[1,1'-biphenyl]-4-yl)benzene;H3BBC;5''-(4'-Carboxy[1,1'-biphenyl]-4-yl)-[1,1':4',1'':3'',1''':4''',1''''-quinquephenyl]-4,4''''-dicarboxylic acid;H3TCBPB;TCBTB;TCBPB;1,3,5-Tris(4'-carboxy[1,1'-biphenyl]-4-yl)benzene 95%

Chemical Property of 1,3,5-Tris(4'-carboxy[1,1'-biphenyl]-4-yl)benzene

Chemical Property:

• Melting Point: 326℃
• Boiling Point: 941.6±65.0 °C(Predicted)
• PKA: 3.65±0.10(Predicted)
• PSA: 111.90000
• Density: 1.285±0.06 g/cm3(Predicted)
• LogP: 10.78320
• Storage Temp.: Sealed in dry,Room Temperature

Purity/Quality:

≥99% ^*data from raw suppliers

1,3,5-Tris(4′-carboxy[1,1′-biphenyl]-4-yl)benzene 95% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1,3,5-Tris(4'-carboxy[1,1'-biphenyl]-4-yl)benzene

There total 3 articles about 1,3,5-Tris(4'-carboxy[1,1'-biphenyl]-4-yl)benzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

C48H36O6 (911818-74-1) → 4,4’,4’’-(benzene-1,3,5-triyl-tris(benzene-4,1-diyl))tribenzoic acid (911818-75-2)

Guidance literature:

C₄₈H₃₆O₆; With water; sodium hydroxide; In tetrahydrofuran; methanol; at 20 ℃; for 48h;

With hydrogenchloride; In water;

Reference yield: 95.4%

4,4''''-dibromo-5''-(4'-bromo-[1,1'-biphenyl]-4-yl)-1,1':4',1'':3'',1''':4''',1''''-quinquephenyl (685114-64-1) + carbon dioxide (124-38-9,18923-20-1) → 4,4’,4’’-(benzene-1,3,5-triyl-tris(benzene-4,1-diyl))tribenzoic acid (911818-75-2)

Guidance literature:

4,4''''-dibromo-5''-(4'-bromo-[1,1'-biphenyl]-4-yl)-1,1':4',1'':3'',1''':4''',1''''-quinquephenyl; With n-butyllithium; In tetrahydrofuran; hexane; at -70.16 ℃; for 6h; Inert atmosphere;

carbon dioxide; In tetrahydrofuran; hexane; at -70 - 20 ℃; Inert atmosphere;

DOI:10.1039/c2dt12072k

Reference yield:

→ 4,4’,4’’-(benzene-1,3,5-triyl-tris(benzene-4,1-diyl))tribenzoic acid (911818-75-2)

Guidance literature:

upstream raw materials:

C₄₈H₃₆O₆

4,4''''-dibromo-5''-(4'-bromo-[1,1'-biphenyl]-4-yl)-1,1':4',1'':3'',1''':4''',1''''-quinquephenyl

carbon dioxide