HEXAAMINENICKEL(II) BROMIDE

Base Information

• Chemical Name: HEXAAMINENICKEL(II) BROMIDE
• CAS No.: 13601-55-3
• Molecular Formula: 2Br*H₁₈N₆Ni
• Molecular Weight: 320.681
• Mol file: 13601-55-3.mol

Synonyms:Hexaamminenickeldibromide (7CI); Nickel(2+), hexaammine-, dibromide (8CI); Hexaamminenickeldibromide (Ni(NH3)6Br2); Hexaamminenickel(2+) dibromide; NSC 43597

Chemical Property of HEXAAMINENICKEL(II) BROMIDE

Chemical Property:

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• PSA: 19.44000
• Density: g/cm³
• LogP: 3.63460

Purity/Quality:

99% ^*data from raw suppliers

HEXAAMMINENICKEL(II) BROMIDE 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T
• Statements: 45-42/43
• Safety Statements: 53-36/37/39-45

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of HEXAAMINENICKEL(II) BROMIDE

There total 6 articles about HEXAAMINENICKEL(II) BROMIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

dibromobis(triphenylphosphine)nickel(II) (36673-36-6,111408-20-9,14126-37-5,54053-52-0) + ammonia (7664-41-7) → hexaamminenickel(II) bromide (13601-55-3)

Guidance literature:

In diethyl ether; ammonia; byproducts: PPh3; absence of moisture; condensation of liquid NH3 into Ni-complex soln. (in ether), stirring (2 h); evapn. of NH3, filtration, distn. off of ether;

Reference yield:

ammonia (7664-41-7) + nickel dibromide (13462-88-9) → hexaamminenickel(II) bromide (13601-55-3)

Guidance literature:

In neat (no solvent); passing gaseous NH3 over moist NiBr2;;

Reference yield:

ammonium bromide + Ni(OH)2*6H2O → hexaamminenickel(II) bromide (13601-55-3)

Guidance literature:

With aq. ammonia; In ammonia; aq. NH3; dissoln. of Ni(OH)2 in ammonia, addn. of ammonia salt, heating (70°C); crystn. on cooling (1°C/day) to room temp.;

DOI:10.1088/0953-8984/6/50/009

upstream raw materials:

ammonia

nickel dibromide

dibromobis(triphenylphosphine)nickel(II)

nickel(II)

Refernces

• 1、 Essmann, R.. "Hydrogen bonding in hexamminemetal(II) bromides Br2 (M2+=Ca2+, Mn2+, Fe2+, Co2+, Ni2+, Cu2+, Cd2+) - synergetic effect of M2+". . p. 91 - 94. Retrieved 1995.