Cyclononanone (2,4-dinitrophenyl)hydrazone

Base Information

• Chemical Name: Cyclononanone (2,4-dinitrophenyl)hydrazone
• CAS No.: 13659-78-4
• Molecular Formula: C₁₅H₂₀N₄O₄
• Molecular Weight: 320.348
• Mol file: 13659-78-4.mol

Synonyms:Cyclononanone (2,4-dinitrophenyl)hydrazone

Chemical Property of Cyclononanone (2,4-dinitrophenyl)hydrazone

Chemical Property:

• Melting Point: 146 °C
• Boiling Point: 471.8±55.0 °C(Predicted)
• PKA: 14.09±0.20(Predicted)
• PSA: 116.03000
• Density: 1.35±0.1 g/cm3(Predicted)
• LogP: 5.52470

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Cyclononanone (2,4-dinitrophenyl)hydrazone

There total 5 articles about Cyclononanone (2,4-dinitrophenyl)hydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

cyclononanone (3350-30-9) + (2,4-dinitro-phenyl)-hydrazine (119-26-6) → cyclononanon-(2,4-dinitro-phenylhydrazone) (13659-78-4)

Guidance literature:

DOI:10.1002/hlca.19470300637

Reference yield:

2-(2-Methylamino-phenylsulfonyl)-cyclononanon (73674-33-6) → cyclononanon-(2,4-dinitro-phenylhydrazone) (13659-78-4)

Guidance literature:

Multi-step reaction with 2 steps

1: Al-Hg / tetrahydrofuran; H₂O / 0.67 h / Heating

2: conc. H₂SO₄ / ethanol / 0.33 h / Heating

With aluminium amalgam; sulfuric acid; In tetrahydrofuran; ethanol; water;

Reference yield:

9-Bromo-nonanoic acid (2-{2-[(9-bromo-nonanoyl)-methyl-amino]-phenyldisulfanyl}-phenyl)-methyl-amide (78082-11-8) → cyclononanon-(2,4-dinitro-phenylhydrazone) (13659-78-4)

Guidance literature:

Multi-step reaction with 5 steps

1: 77.3 percent / NaBH₄, NaH, 2-propanol / dioxane / 1.) 70 deg C, 2.) reflux, 1 h

2: 94.8 percent / m-chloroperbenzoic acid / CH₂Cl₂ / Ambient temperature

3: tert-BuOK / dimethylsulfoxide; tetrahydrofuran / 0.17 h / Ambient temperature

4: Al-Hg / tetrahydrofuran; H₂O / 0.67 h / Heating

5: conc. H₂SO₄ / ethanol / 0.33 h / Heating

With sodium tetrahydroborate; aluminium amalgam; sulfuric acid; potassium tert-butylate; sodium hydride; 3-chloro-benzenecarboperoxoic acid; isopropyl alcohol; In tetrahydrofuran; 1,4-dioxane; ethanol; dichloromethane; water; dimethyl sulfoxide;

upstream raw materials:

cyclononanone

(2,4-dinitro-phenyl)-hydrazine

2-(2-Methylamino-phenylsulfonyl)-cyclononanon

9-Bromo-nonanoic acid (2-{2-[(9-bromo-nonanoyl)-methyl-amino]-phenyldisulfanyl}-phenyl)-methyl-amide