(R)-tetrahydro-2-<<<1(e)-allyl-2(e)-isopropyl-5(e)-methylcyclohexanyl>oxy>methyl>-2-furanmethanol

Base Information

Chemical Name:(R)-tetrahydro-2-<<<1(e)-allyl-2(e)-isopropyl-5(e)-methylcyclohexanyl>oxy>methyl>-2-furanmethanol
CAS No.:173974-63-5
Molecular Formula:C₁₉H₃₄O₃
Molecular Weight:310.477
Hs Code.:

Synonyms:(R)-tetrahydro-2-<<<1(e)-allyl-2(e)-isopropyl-5(e)-methylcyclohexanyl>oxy>methyl>-2-furanmethanol

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Chemical Property of (R)-tetrahydro-2-<<<1(e)-allyl-2(e)-isopropyl-5(e)-methylcyclohexanyl>oxy>methyl>-2-furanmethanol

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Technology Process of (R)-tetrahydro-2-<<<1(e)-allyl-2(e)-isopropyl-5(e)-methylcyclohexanyl>oxy>methyl>-2-furanmethanol

There total 3 articles about (R)-tetrahydro-2-<<<1(e)-allyl-2(e)-isopropyl-5(e)-methylcyclohexanyl>oxy>methyl>-2-furanmethanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.9%

: (9S,12R)-9-Isopropyl-12-methyl-1,7,14-trioxa-dispiro[4.2.5.2]pentadecane

: 762-72-1
allyl-trimethyl-silane

: 173974-63-5
(R)-tetrahydro-2-<<<1(e)-allyl-2(e)-isopropyl-5(e)-methylcyclohexanyl>oxy>methyl>-2-furanmethanol

Guidance literature:: With titanium tetrachloride; In dichloromethane; at -90 ℃; for 0.5h;
DOI:10.1021/jo9515034

Reference yield:

: 13386-57-7
2,2-bis(hydroxymethyl)-tetrahydrofuran

: 173974-63-5
(R)-tetrahydro-2-<<<1(e)-allyl-2(e)-isopropyl-5(e)-methylcyclohexanyl>oxy>methyl>-2-furanmethanol

Guidance literature:: Multi-step reaction with 3 steps

1: 82 percent / hexamethyldisilazane / tetrahydrofuran / 0.5 h / 5 °C

2: TMSOTf / CH₂Cl₂ / 22 h / -40 °C

3: 96.9 percent / TiCl₄ / CH₂Cl₂ / 0.5 h / -90 °C

With trimethylsilyl trifluoromethanesulfonate; titanium tetrachloride; 1,1,1,3,3,3-hexamethyl-disilazane; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo9515034

Reference yield:

: 173974-61-3
tetrahydro-2,2-bis(((trimethylsilyl)oxy)methyl)furan

: 173974-63-5
(R)-tetrahydro-2-<<<1(e)-allyl-2(e)-isopropyl-5(e)-methylcyclohexanyl>oxy>methyl>-2-furanmethanol

Guidance literature:: Multi-step reaction with 2 steps

1: TMSOTf / CH₂Cl₂ / 22 h / -40 °C

2: 96.9 percent / TiCl₄ / CH₂Cl₂ / 0.5 h / -90 °C

With trimethylsilyl trifluoromethanesulfonate; titanium tetrachloride; In dichloromethane;
DOI:10.1021/jo9515034