(3R,4R)-3-hydroxy-2-benzoyloxycyclohexanone

Base Information

Chemical Name:(3R,4R)-3-hydroxy-2-benzoyloxycyclohexanone
CAS No.:405556-18-5
Molecular Formula:C₁₃H₁₄O₄
Molecular Weight:234.252
Hs Code.:

Synonyms:(3R,4R)-3-hydroxy-2-benzoyloxycyclohexanone

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3R,4R)-3-hydroxy-2-benzoyloxycyclohexanone

Chemical Property:

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Technology Process of (3R,4R)-3-hydroxy-2-benzoyloxycyclohexanone

There total 4 articles about (3R,4R)-3-hydroxy-2-benzoyloxycyclohexanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 405556-17-4
(1R,2R)-2-benzoyloxy-5-methylenecyclohexanol

: 405556-18-5
(3R,4R)-3-hydroxy-2-benzoyloxycyclohexanone

Guidance literature:: (1R,2R)-2-benzoyloxy-5-methylenecyclohexanol; With ozone; In methanol; dichloromethane; at -78 ℃;

With dimethylsulfide; In methanol; dichloromethane; at -78 - 20 ℃; Further stages.;
DOI:10.1039/b107085a

Reference yield:

: 405556-16-3
(2R)-2-benzoyloxy-5-methylhex-5-enal

: 405556-18-5
(3R,4R)-3-hydroxy-2-benzoyloxycyclohexanone

Guidance literature:: Multi-step reaction with 2 steps

1.1: 95 percent / 4 Angstroem molecular sieves / CH₂Cl₂ / 48 h

2.1: ozone / CH₂Cl₂; methanol / -78 °C

2.2: 95 percent / Me₂S / CH₂Cl₂; methanol / -78 - 20 °C

With 4 A molecular sieve; ozone; In methanol; dichloromethane;
DOI:10.1039/b107085a

Reference yield:

: 197365-66-5
(5R,6R,7R,8R)-2,11-dimethyl-5,8-bis(benzoyloxy)-6,7-isopropylidenedioxydodeca-1,11-diene

: 405556-18-5
(3R,4R)-3-hydroxy-2-benzoyloxycyclohexanone

Guidance literature:: Multi-step reaction with 4 steps

1.1: 81 percent / PTSA / methanol / 8 h / Heating

2.1: 91 percent / lead tetraacetate / CH₂Cl₂ / 1 h / -20 °C

3.1: 95 percent / 4 Angstroem molecular sieves / CH₂Cl₂ / 48 h

4.1: ozone / CH₂Cl₂; methanol / -78 °C

4.2: 95 percent / Me₂S / CH₂Cl₂; methanol / -78 - 20 °C

With lead(IV) acetate; 4 A molecular sieve; toluene-4-sulfonic acid; ozone; In methanol; dichloromethane;
DOI:10.1039/b107085a