β-D-arabinofuranose 1,2,5-orthobenzoate

Base Information

• Chemical Name: β-D-arabinofuranose 1,2,5-orthobenzoate
• CAS No.: 282107-49-7
• Molecular Formula: C₁₂H₁₂O₅
• Molecular Weight: 236.224
• Mol file: 282107-49-7.mol

Synonyms:β-D-arabinofuranose 1,2,5-orthobenzoate

Chemical Property of β-D-arabinofuranose 1,2,5-orthobenzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of β-D-arabinofuranose 1,2,5-orthobenzoate

There total 8 articles about β-D-arabinofuranose 1,2,5-orthobenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

(3aS,5R,6R,6aS)-5-Hydroxymethyl-2-methoxy-2-phenyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol (502761-67-3) → β-D-arabinofuranose 1,2,5-orthobenzoate (282107-49-7)

Guidance literature:

With 4 A molecular sieve; camphor-10-sulfonic acid; In dichloromethane; at 20 ℃; for 0.5h;

DOI:10.1002/1099-0690(200211)2002:22<3864::AID-EJOC3864>3.0.CO;2-8

Reference yield: 78.0%

β-D-arabinfuranose 1,2-(methyl)orthobenzoate → β-D-arabinofuranose 1,2,5-orthobenzoate (282107-49-7)

Guidance literature:

With magnesium bromide; In tetrahydrofuran; at 55 ℃; for 2h; Inert atmosphere;

DOI:10.1007/s11172-010-0038-y

Reference yield: 70.0%

C27H24O8 → β-D-arabinofuranose 1,2,5-orthobenzoate (282107-49-7)

Guidance literature:

C₂₇H₂₄O₈; With sodium methylate; In methanol; at 20 ℃; for 16h;

With toluene-4-sulfonic acid; In 1,2-dichloro-ethane; Molecular sieve; Reflux;

DOI:10.1016/j.carres.2010.11.002

upstream raw materials:

(3aS,5R,6R,6aS)-5-Hydroxymethyl-2-methoxy-2-phenyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol

methyl tri-O-benzoyl-α-D-arabinofuranoside

C₁₃H₁₆O₆C₁₄H₈O₂

2,3,5-tetra-O-benzoyl-α-D-arabinofuranosyl chloride

Downstream raw materials:

octyl 2-O-benzoyl-α-D-arabinofuranoside

3-O-acetyl-β-D-arabinofuranose 1,2,5-orthobenzoate

3-O-benzoyl-β-D-arabinofuranose 1,2,5-orthobenzoate

3-O-chloroacetyl-β-D-arabinofuranose 1,2,5-orthobenzoate