(3aS,5R,6R,6aS)-5-Hydroxymethyl-2-methoxy-2-phenyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol

Base Information

Chemical Name:(3aS,5R,6R,6aS)-5-Hydroxymethyl-2-methoxy-2-phenyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol
CAS No.:502761-67-3
Molecular Formula:C₁₃H₁₆O₆
Molecular Weight:268.266
Hs Code.:

Synonyms:(3aS,5R,6R,6aS)-5-Hydroxymethyl-2-methoxy-2-phenyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol

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Chemical Property of (3aS,5R,6R,6aS)-5-Hydroxymethyl-2-methoxy-2-phenyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol

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Technology Process of (3aS,5R,6R,6aS)-5-Hydroxymethyl-2-methoxy-2-phenyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol

There total 2 articles about (3aS,5R,6R,6aS)-5-Hydroxymethyl-2-methoxy-2-phenyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 502761-66-2
C₁₃H₁₆O₆C₁₄H₈O₂

: 502761-67-3
(3aS,5R,6R,6aS)-5-Hydroxymethyl-2-methoxy-2-phenyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol

Guidance literature:: With sodium methylate; In methanol; at 20 ℃;
DOI:10.1002/1099-0690(200211)2002:22<3864::AID-EJOC3864>3.0.CO;2-8

Reference yield:

: 7473-42-9,22861-07-0,38837-17-1,42793-97-5,52783-53-6,52783-87-6,69350-76-1,69927-20-4,84518-41-2,103238-80-8,105309-18-0,109959-28-6,109959-29-7,114923-83-0,120964-98-9
methyl tri-O-benzoyl-α-D-arabinofuranoside

: 502761-67-3
(3aS,5R,6R,6aS)-5-Hydroxymethyl-2-methoxy-2-phenyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol

Guidance literature:: Multi-step reaction with 2 steps

1.1: CH₃OCHCl₂; SnCl₄ / CH₂Cl₂ / 8 h / 20 °C

1.2: 86 percent / NEt₃; nBu₄NBr; 3 Angstroem molecular sieves / CH₂Cl₂ / 16 h / 20 °C

2.1: 92 percent / MeONa / methanol / 20 °C

With Dichloromethyl methyl ether; sodium methylate; tin(IV) chloride; In methanol; dichloromethane;
DOI:10.1002/1099-0690(200211)2002:22<3864::AID-EJOC3864>3.0.CO;2-8

Reference yield: 86.0%

: 502761-67-3
(3aS,5R,6R,6aS)-5-Hydroxymethyl-2-methoxy-2-phenyl-tetrahydro-furo[2,3-d][1,3]dioxol-6-ol

: 282107-49-7
β-D-arabinofuranose 1,2,5-orthobenzoate

Guidance literature:: With 4 A molecular sieve; camphor-10-sulfonic acid; In dichloromethane; at 20 ℃; for 0.5h;
DOI:10.1002/1099-0690(200211)2002:22<3864::AID-EJOC3864>3.0.CO;2-8