(1R,2S,3R)-1-[(4-methoxybenzyloxy)methyl]-2,3-bis(4-methoxybenzyloxy)-4-hydroxybutyl (2E)-2-methyl-3-[1,3-dimethyl-2-oxo-4-[(1E,3S,4R,5S)-1,3,5-trimethyl-4-(4-methoxybenzyloxy)-1-pentadecenyl]-3-cyclohexenyl]propenoate

Base Information

Chemical Name:(1R,2S,3R)-1-[(4-methoxybenzyloxy)methyl]-2,3-bis(4-methoxybenzyloxy)-4-hydroxybutyl (2E)-2-methyl-3-[1,3-dimethyl-2-oxo-4-[(1E,3S,4R,5S)-1,3,5-trimethyl-4-(4-methoxybenzyloxy)-1-pentadecenyl]-3-cyclohexenyl]propenoate
CAS No.:637740-87-5
Molecular Formula:C₆₇H₉₂O₁₂
Molecular Weight:1089.46
Hs Code.:

(1R,2S,3R)-1-[(4-methoxybenzyloxy)methyl]-2,3-bis(4-methoxybenzyloxy)-4-hydroxybutyl (2E)-2-methyl-3-[1,3-dimethyl-2-oxo-4-[(1E,3S,4R,5S)-1,3,5-trimethyl-4-(4-methoxybenzyloxy)-1-pentadecenyl]-3-cyclohexenyl]propenoate

Synonyms:(1R,2S,3R)-1-[(4-methoxybenzyloxy)methyl]-2,3-bis(4-methoxybenzyloxy)-4-hydroxybutyl (2E)-2-methyl-3-[1,3-dimethyl-2-oxo-4-[(1E,3S,4R,5S)-1,3,5-trimethyl-4-(4-methoxybenzyloxy)-1-pentadecenyl]-3-cyclohexenyl]propenoate

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Chemical Property of (1R,2S,3R)-1-[(4-methoxybenzyloxy)methyl]-2,3-bis(4-methoxybenzyloxy)-4-hydroxybutyl (2E)-2-methyl-3-[1,3-dimethyl-2-oxo-4-[(1E,3S,4R,5S)-1,3,5-trimethyl-4-(4-methoxybenzyloxy)-1-pentadecenyl]-3-cyclohexenyl]propenoate

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Technology Process of (1R,2S,3R)-1-[(4-methoxybenzyloxy)methyl]-2,3-bis(4-methoxybenzyloxy)-4-hydroxybutyl (2E)-2-methyl-3-[1,3-dimethyl-2-oxo-4-[(1E,3S,4R,5S)-1,3,5-trimethyl-4-(4-methoxybenzyloxy)-1-pentadecenyl]-3-cyclohexenyl]propenoate

There total 7 articles about (1R,2S,3R)-1-[(4-methoxybenzyloxy)methyl]-2,3-bis(4-methoxybenzyloxy)-4-hydroxybutyl (2E)-2-methyl-3-[1,3-dimethyl-2-oxo-4-[(1E,3S,4R,5S)-1,3,5-trimethyl-4-(4-methoxybenzyloxy)-1-pentadecenyl]-3-cyclohexenyl]propenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 3-{4-[4-(4-methoxy-benzyloxy)-1,3,5-trimethyl-pentadec-1-enyl]-1,3-dimethyl-2-oxo-cyclohex-3-enyl}-2-methyl-acrylic acid 4-(tert-butyl-dimethyl-silanyloxy)-2,3-bis-(4-methoxy-benzyloxy)-1-(4-methoxy-benzyloxymethyl)-butyl ester

: 637740-87-5
(1R,2S,3R)-1-[(4-methoxybenzyloxy)methyl]-2,3-bis(4-methoxybenzyloxy)-4-hydroxybutyl (2E)-2-methyl-3-[1,3-dimethyl-2-oxo-4-[(1E,3S,4R,5S)-1,3,5-trimethyl-4-(4-methoxybenzyloxy)-1-pentadecenyl]-3-cyclohexenyl]propenoate

Guidance literature:: With hydrogenchloride; In tetrahydrofuran; at 20 ℃; for 6h;
DOI:10.1039/b305818b

Reference yield:

: 81465-44-3
3-Iodo-2,6-dimethyl-cyclohex-2-enone

: 637740-87-5
(1R,2S,3R)-1-[(4-methoxybenzyloxy)methyl]-2,3-bis(4-methoxybenzyloxy)-4-hydroxybutyl (2E)-2-methyl-3-[1,3-dimethyl-2-oxo-4-[(1E,3S,4R,5S)-1,3,5-trimethyl-4-(4-methoxybenzyloxy)-1-pentadecenyl]-3-cyclohexenyl]propenoate

Guidance literature:: Multi-step reaction with 7 steps

1.1: 62 percent / aq. NaOH / dioxane / 0.5 h / 20 °C

2.1: 92 percent / oxalyl chloride; DMSO; triethylamine / CH₂Cl₂ / -78 - 20 °C

3.1: 97 percent / toluene / 20 h / Heating

4.1: 54 percent / iodotrimethylsilane / 5 h / Heating

5.1: 66 percent / 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride; N,N-dimethylaminopyridine / CH₂Cl₂ / 5 h / Heating

6.1: 9-BBN / tetrahydrofuran / 24 h / 20 °C

6.2: K₃PO₄ / PdCl₂(dppf) / dimethylformamide; H₂O / 1 h / 50 °C

7.1: 61 mg / aq. HCl / tetrahydrofuran / 6 h / 20 °C

With hydrogenchloride; dmap; sodium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; oxalyl dichloride; trimethylsilyl iodide; dimethyl sulfoxide; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; In tetrahydrofuran; 1,4-dioxane; dichloromethane; toluene; 2.1: Swern oxidation / 6.2: Suzuki-Miyaura coupling;
DOI:10.1039/b305818b

Reference yield:

: 637741-38-9
4-iodo-1,3-dimethyl-2-oxo-cyclohex-3-enecarbaldehyde

: 637740-87-5
(1R,2S,3R)-1-[(4-methoxybenzyloxy)methyl]-2,3-bis(4-methoxybenzyloxy)-4-hydroxybutyl (2E)-2-methyl-3-[1,3-dimethyl-2-oxo-4-[(1E,3S,4R,5S)-1,3,5-trimethyl-4-(4-methoxybenzyloxy)-1-pentadecenyl]-3-cyclohexenyl]propenoate

Guidance literature:: Multi-step reaction with 5 steps

1.1: 97 percent / toluene / 20 h / Heating

2.1: 54 percent / iodotrimethylsilane / 5 h / Heating

3.1: 66 percent / 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride; N,N-dimethylaminopyridine / CH₂Cl₂ / 5 h / Heating

4.1: 9-BBN / tetrahydrofuran / 24 h / 20 °C

4.2: K₃PO₄ / PdCl₂(dppf) / dimethylformamide; H₂O / 1 h / 50 °C

5.1: 61 mg / aq. HCl / tetrahydrofuran / 6 h / 20 °C

With hydrogenchloride; dmap; 9-borabicyclo[3.3.1]nonane dimer; trimethylsilyl iodide; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; In tetrahydrofuran; dichloromethane; toluene; 4.2: Suzuki-Miyaura coupling;
DOI:10.1039/b305818b