(2R,3R,5E,9Z)-2,3,6,10-tetramethyl-8-phenylsulfonyl-5,9-dodecadien-1-ol THP ether

Base Information

Chemical Name:(2R,3R,5E,9Z)-2,3,6,10-tetramethyl-8-phenylsulfonyl-5,9-dodecadien-1-ol THP ether
CAS No.:78094-74-3
Molecular Formula:C₂₇H₄₂O₄S
Molecular Weight:462.694
Hs Code.:

Synonyms:(2R,3R,5E,9Z)-2,3,6,10-tetramethyl-8-phenylsulfonyl-5,9-dodecadien-1-ol THP ether

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Chemical Property of (2R,3R,5E,9Z)-2,3,6,10-tetramethyl-8-phenylsulfonyl-5,9-dodecadien-1-ol THP ether

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Technology Process of (2R,3R,5E,9Z)-2,3,6,10-tetramethyl-8-phenylsulfonyl-5,9-dodecadien-1-ol THP ether

There total 30 articles about (2R,3R,5E,9Z)-2,3,6,10-tetramethyl-8-phenylsulfonyl-5,9-dodecadien-1-ol THP ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 78094-73-2,83377-56-4,83377-57-5
2-((E)-(2S,3R)-7-Bromo-2,3,6-trimethyl-hept-5-enyloxy)-tetrahydro-pyran

: Benzenesulfinic acid (Z)-3-methyl-pent-2-enyl ester

: 78094-74-3
(2R,3R,5E,9Z)-2,3,6,10-tetramethyl-8-phenylsulfonyl-5,9-dodecadien-1-ol THP ether

Guidance literature:: With n-butyllithium; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide;
DOI:10.1016/0040-4039(81)80126-8

Reference yield:

: 38342-07-3
(Z)-3-methyl-1-bromo-2-pentene

: 78094-74-3
(2R,3R,5E,9Z)-2,3,6,10-tetramethyl-8-phenylsulfonyl-5,9-dodecadien-1-ol THP ether

Guidance literature:: Multi-step reaction with 2 steps

1: 89 percent / dimethylformamide / 6 h / Ambient temperature

2: 1) n-BuLi / 1) n-hexane, dry THF-HMPA, 1 h, -20 deg C, 2) dry THF, -65 deg C, 2 h

With n-butyllithium; In N,N-dimethyl-formamide;
DOI:10.1016/0040-4020(82)85108-9

Reference yield:

: 873-55-2
sodium benzenesulfonate

: 78094-74-3
(2R,3R,5E,9Z)-2,3,6,10-tetramethyl-8-phenylsulfonyl-5,9-dodecadien-1-ol THP ether

Guidance literature:: Multi-step reaction with 2 steps

1: 89 percent / dimethylformamide / 6 h / Ambient temperature

2: 1) n-BuLi / 1) n-hexane, dry THF-HMPA, 1 h, -20 deg C, 2) dry THF, -65 deg C, 2 h

With n-butyllithium; In N,N-dimethyl-formamide;
DOI:10.1016/0040-4020(82)85108-9