3,6-di-tert-butyl-9-[(3-tert-butyl-5-methylcyclopenta-1,4-dienyl)-phenylethyl]-9H-fluorene

Base Information

Chemical Name:3,6-di-tert-butyl-9-[(3-tert-butyl-5-methylcyclopenta-1,4-dienyl)-phenylethyl]-9H-fluorene
CAS No.:916991-52-1
Molecular Formula:C₃₈H₄₆
Molecular Weight:502.783
Hs Code.:

Synonyms:3,6-di-tert-butyl-9-[(3-tert-butyl-5-methylcyclopenta-1,4-dienyl)-phenylethyl]-9H-fluorene

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Chemical Property of 3,6-di-tert-butyl-9-[(3-tert-butyl-5-methylcyclopenta-1,4-dienyl)-phenylethyl]-9H-fluorene

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Technology Process of 3,6-di-tert-butyl-9-[(3-tert-butyl-5-methylcyclopenta-1,4-dienyl)-phenylethyl]-9H-fluorene

There total 1 articles about 3,6-di-tert-butyl-9-[(3-tert-butyl-5-methylcyclopenta-1,4-dienyl)-phenylethyl]-9H-fluorene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 916991-51-0
3-tert-butyl-1-isopropyl-6-phenylfulvene

: 58775-07-8
3,6-di-tert-butyl-9H-fluorene

: 916991-52-1
3,6-di-tert-butyl-9-[(3-tert-butyl-5-methylcyclopenta-1,4-dienyl)-phenylethyl]-9H-fluorene

Guidance literature:: 3,6-di-tert-butyl-9H-fluorene; With n-butyllithium; In hexane; Inert atmosphere;

3-tert-butyl-1-isopropyl-6-phenylfulvene; In tetrahydrofuran; hexane; at 20 ℃; for 4h; Inert atmosphere;
DOI:10.1021/om100897j

Reference yield: 88.0%

: 916991-52-1
3,6-di-tert-butyl-9-[(3-tert-butyl-5-methylcyclopenta-1,4-dienyl)-phenylethyl]-9H-fluorene

: 10026-11-6
zirconium(IV) chloride

: 917083-58-0,1260509-86-1
[(Ph(H)C-(3,6-(t-Bu)2-fluorenyl)(3-t-Bu-5-Me-C₅H₂))ZrCl₂]

Guidance literature:: With n-BuLi; In diethyl ether; hexane; byproducts: LiCl; (Ar); std. Schlenk technique; soln. of BuLi in hexane was added with stirring to soln. of fluorene in Et2O at 0°C; after 12 h ZrCl4 was added; stirred at room temp. overnight; evapd. (vac.); hexane transferred in vac.; filtered; solvent removed;
DOI:10.1021/om100897j