(E)-(2R,2'S,4'R)-(-)-1-(4-allyl-2-phenyl-1,3-dioxan-5-ylideneamino)-2-(methoxymethyl)pyrrolidine

Base Information

Chemical Name:(E)-(2R,2'S,4'R)-(-)-1-(4-allyl-2-phenyl-1,3-dioxan-5-ylideneamino)-2-(methoxymethyl)pyrrolidine
CAS No.:288069-37-4
Molecular Formula:C₁₉H₂₆N₂O₃
Molecular Weight:330.427
Hs Code.:

Synonyms:(E)-(2R,2'S,4'R)-(-)-1-(4-allyl-2-phenyl-1,3-dioxan-5-ylideneamino)-2-(methoxymethyl)pyrrolidine

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Chemical Property of (E)-(2R,2'S,4'R)-(-)-1-(4-allyl-2-phenyl-1,3-dioxan-5-ylideneamino)-2-(methoxymethyl)pyrrolidine

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Technology Process of (E)-(2R,2'S,4'R)-(-)-1-(4-allyl-2-phenyl-1,3-dioxan-5-ylideneamino)-2-(methoxymethyl)pyrrolidine

There total 1 articles about (E)-(2R,2'S,4'R)-(-)-1-(4-allyl-2-phenyl-1,3-dioxan-5-ylideneamino)-2-(methoxymethyl)pyrrolidine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 106-95-6
allyl bromide

: (2R,2'S)-(-)-1-(2-phenyl-1,3-dioxan-5-ylideneamino)-2-(methoxymethyl)pyrrolidine

: 288069-37-4
(E)-(2R,2'S,4'R)-(-)-1-(4-allyl-2-phenyl-1,3-dioxan-5-ylideneamino)-2-(methoxymethyl)pyrrolidine

Guidance literature:: With tert.-butyl lithium; In tetrahydrofuran; pentane; at -100 ℃; for 2h;
DOI:10.1002/1099-0690(200109)2001:17<3367::AID-EJOC3367>3.0.CO;2-H

Reference yield: 97.0%

: 288069-37-4
(E)-(2R,2'S,4'R)-(-)-1-(4-allyl-2-phenyl-1,3-dioxan-5-ylideneamino)-2-(methoxymethyl)pyrrolidine

: 288069-39-6
(2S,4R)-(+)-4-allyl-2-phenyl-1,3-dioxan-5-one

Guidance literature:: With ammonium dihydrogen phosphate; In tetrahydrofuran; water; at 20 ℃; for 8h; pH=4.5;
DOI:10.1002/1099-0690(200012)2000:24<3971::AID-EJOC3971>3.0.CO;2-N

Reference yield:

: 288069-37-4
(E)-(2R,2'S,4'R)-(-)-1-(4-allyl-2-phenyl-1,3-dioxan-5-ylideneamino)-2-(methoxymethyl)pyrrolidine

: (+)-3,5-O-benzylidene-2,6-dideoxy-D-lyxo-hexoaldose

Guidance literature:: Multi-step reaction with 4 steps

1: 92 percent / tBuLi / tetrahydrofuran; pentane / 2 h / -100 °C

2: 65 percent / NH₄H₂PO₄; water / tetrahydrofuran / 72 h / 20 °C

3: 95 percent / NaBH₄ / tetrahydrofuran; H₂O / 0.5 h / 0 °C

4: 91 percent / ozone / methanol / 0.5 h / -78 °C

With ammonium dihydrogen phosphate; sodium tetrahydroborate; water; tert.-butyl lithium; ozone; In tetrahydrofuran; methanol; water; pentane;
DOI:10.1002/1099-0690(200109)2001:17<3367::AID-EJOC3367>3.0.CO;2-H