288069-39-6

Basic information

• Product Name: (2S,4R)-(+)-4-allyl-2-phenyl-1,3-dioxan-5-one
• Synonyms: (2S,4R)-(+)-4-allyl-2-phenyl-1,3-dioxan-5-one
• CAS NO: 288069-39-6
• Molecular Weight: 218.252
• Mol File: 288069-39-6.mol

Chemical Properties

• CAS DataBase Reference: (2S,4R)-(+)-4-allyl-2-phenyl-1,3-dioxan-5-one(CAS DataBase Reference)
• NIST Chemistry Reference: (2S,4R)-(+)-4-allyl-2-phenyl-1,3-dioxan-5-one(288069-39-6)
• EPA Substance Registry System: (2S,4R)-(+)-4-allyl-2-phenyl-1,3-dioxan-5-one(288069-39-6)

Safety Data

• Hazardous Substances Data: 288069-39-6(Hazardous Substances Data)

Upstream product

• 1125-88-8 benzaldehyde dimethyl acetal 
• 382593-86-4 (2S,4R,5R)-(+)-4-allyl-2-phenyl-1,3-dioxan-5-ol 
• 288069-37-4 (E)-(2R,2'S,4'R)-(-)-1-(4-allyl-2-phenyl-1,3-dioxan-5-ylideneamino)-2-(methoxymethyl)pyrrolidine 

Downstream Products

• 382593-86-4 (2S,4R,5R)-(+)-4-allyl-2-phenyl-1,3-dioxan-5-ol 

Relevant articles and documents

A method for the selective hydrolysis of ketone hydrazones in the presence of acetals

Dimethylhydrazones and RAMP-hydrazones containing acetal or olefin groups were hydrolysed selectively to form the corresponding ketones, by treatment with ammonium dihydrogen phosphate buffer solutions.

Synthesis of Luffarin L and 16- epi -Luffarin L Using a Temporary Silicon-Tethered Ring-Closing Metathesis Reaction

The first synthesis of luffarin L (1) and 16-epi-luffarin L (2) by a silicon-tethered ring closing metathesis as a key step has been achieved. The stereochemistry and absolute configuration of the natural sesterterpenolide luffarin L (1) and a new route f

Synthesis of all diastereomers of the 2-deoxypentoses and the 2,6-dideoxyhexoses from 2-phenyl-1,3-dioxan-5-one hydrate

All diastereomers of the 2-deoxypentoses and the 2,6-dideoxyhexoses were synthesized from 2-phenyl-1,3-dioxan-5-one hydrate (1), by alkylation via the RAMP-hydrazone (2). Some of the diastereomers were synthesized in the racemic form via the dimethylhydrazone (28). The 2-deoxypentoses were synthesized by alkylation with allyl bromide, followed by stereoselective reduction, ozonolysis, and deprotection. The 2,6-dideoxypentoses were synthesized by dialkylation with allyl bromide and methyl iodide.