phenyl 4-O-(2,4,6-tri-O-benzyl-3-oximino-β-D-xylo-hexopyranosyl)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

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Chemical Name:phenyl 4-O-(2,4,6-tri-O-benzyl-3-oximino-β-D-xylo-hexopyranosyl)-2,3,6-tri-O-benzyl-β-D-glucopyranoside
CAS No.:847237-71-2
Molecular Formula:C₆₀H₆₁NO₁₁
Molecular Weight:972.144
Hs Code.:

Synonyms:phenyl 4-O-(2,4,6-tri-O-benzyl-3-oximino-β-D-xylo-hexopyranosyl)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

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Chemical Property of phenyl 4-O-(2,4,6-tri-O-benzyl-3-oximino-β-D-xylo-hexopyranosyl)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

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Technology Process of phenyl 4-O-(2,4,6-tri-O-benzyl-3-oximino-β-D-xylo-hexopyranosyl)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

There total 3 articles about phenyl 4-O-(2,4,6-tri-O-benzyl-3-oximino-β-D-xylo-hexopyranosyl)-2,3,6-tri-O-benzyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 847237-69-8
phenyl 4-O-(2,4,6-tri-O-benzyl-3-keto-β-D-xylo-hexopyranosyl)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

: 847237-71-2
phenyl 4-O-(2,4,6-tri-O-benzyl-3-oximino-β-D-xylo-hexopyranosyl)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

Guidance literature:: With hydroxylamine hydrochloride; In pyridine; ethanol; at 20 ℃;
DOI:10.1016/j.carres.2004.11.017

Reference yield:

: 847237-68-7
phenyl 4-O-(2,4,6-tri-O-benzyl-β-D-galactopyranosyl)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

: 847237-71-2
phenyl 4-O-(2,4,6-tri-O-benzyl-3-oximino-β-D-xylo-hexopyranosyl)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 2 steps

1: 93 percent / oxalyl chloride; DMSO; Et₃N / CH₂Cl₂ / -78 °C

2: 88 percent / hydroxylamine hydrochloride / pyridine; ethanol / 20 °C

With oxalyl dichloride; hydroxylamine hydrochloride; dimethyl sulfoxide; triethylamine; In pyridine; ethanol; dichloromethane;
DOI:10.1016/j.carres.2004.11.017

Reference yield:

: 847237-67-6
phenyl 4-O-(3-O-allyl-2,4,6-tri-O-benzyl-β-D-galactopyranosyl)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

: 847237-71-2
phenyl 4-O-(2,4,6-tri-O-benzyl-3-oximino-β-D-xylo-hexopyranosyl)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 3 steps

1: 81 percent / tris(triphenylphosphine)rhodium(I) chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene / ethanol; toluene; H₂O / 24 h / Heating

2: 93 percent / oxalyl chloride; DMSO; Et₃N / CH₂Cl₂ / -78 °C

3: 88 percent / hydroxylamine hydrochloride / pyridine; ethanol / 20 °C

With Wilkinson's catalyst; oxalyl dichloride; hydroxylamine hydrochloride; dimethyl sulfoxide; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; In pyridine; ethanol; dichloromethane; water; toluene;
DOI:10.1016/j.carres.2004.11.017