phenyl 4-O-(3-O-allyl-2,4,6-tri-O-benzyl-β-D-galactopyranosyl)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

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Chemical Name:phenyl 4-O-(3-O-allyl-2,4,6-tri-O-benzyl-β-D-galactopyranosyl)-2,3,6-tri-O-benzyl-β-D-glucopyranoside
CAS No.:847237-67-6
Molecular Formula:C₆₃H₆₆O₁₁
Molecular Weight:999.21
Hs Code.:

Synonyms:phenyl 4-O-(3-O-allyl-2,4,6-tri-O-benzyl-β-D-galactopyranosyl)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

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Chemical Property of phenyl 4-O-(3-O-allyl-2,4,6-tri-O-benzyl-β-D-galactopyranosyl)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

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Technology Process of phenyl 4-O-(3-O-allyl-2,4,6-tri-O-benzyl-β-D-galactopyranosyl)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

There total 1 articles about phenyl 4-O-(3-O-allyl-2,4,6-tri-O-benzyl-β-D-galactopyranosyl)-2,3,6-tri-O-benzyl-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 100-39-0
benzyl bromide

: 847237-65-4
phenyl 4-O-(3-O-allyl-β-D-galactopyranosyl)-β-D-glucopyranoside

: 847237-67-6
phenyl 4-O-(3-O-allyl-2,4,6-tri-O-benzyl-β-D-galactopyranosyl)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide;
DOI:10.1016/j.carres.2004.11.017

Reference yield: 81.0%

: 847237-67-6
phenyl 4-O-(3-O-allyl-2,4,6-tri-O-benzyl-β-D-galactopyranosyl)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

: 847237-68-7
phenyl 4-O-(2,4,6-tri-O-benzyl-β-D-galactopyranosyl)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

Guidance literature:: With Wilkinson's catalyst; 1,8-diazabicyclo[5.4.0]undec-7-ene; In ethanol; water; toluene; for 24h; Heating;
DOI:10.1016/j.carres.2004.11.017

Reference yield:

: 847237-67-6
phenyl 4-O-(3-O-allyl-2,4,6-tri-O-benzyl-β-D-galactopyranosyl)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

: 847237-72-3
phenyl 4-O-(3-acetamido-2,4,6-tri-O-benzyl-3-deoxy-β-D-galactopyranosyl)-2,3,6-tri-O-benzyl-β-D-glucopyranoside

Guidance literature:: Multi-step reaction with 5 steps

1: 81 percent / tris(triphenylphosphine)rhodium(I) chloride; 1,8-diazabicyclo[5.4.0]undec-7-ene / ethanol; toluene; H₂O / 24 h / Heating

2: 93 percent / oxalyl chloride; DMSO; Et₃N / CH₂Cl₂ / -78 °C

3: 88 percent / hydroxylamine hydrochloride / pyridine; ethanol / 20 °C

4: LiAlH₄ / tetrahydrofuran / 20 °C

5: 77 mg / pyridine / 20 °C

With Wilkinson's catalyst; lithium aluminium tetrahydride; oxalyl dichloride; hydroxylamine hydrochloride; dimethyl sulfoxide; 1,8-diazabicyclo[5.4.0]undec-7-ene; triethylamine; In tetrahydrofuran; pyridine; ethanol; dichloromethane; water; toluene;
DOI:10.1016/j.carres.2004.11.017