endo-6,syn-7-dichlorobicyclo[3.1.1]hept-endo-6-yl phenyl sulfone

Base Information

• Chemical Name: endo-6,syn-7-dichlorobicyclo[3.1.1]hept-endo-6-yl phenyl sulfone
• CAS No.: 1115244-04-6
• Molecular Formula: C₁₃H₁₄Cl₂O₂S
• Molecular Weight: 305.225
• Mol file: 1115244-04-6.mol

Synonyms:endo-6,syn-7-dichlorobicyclo[3.1.1]hept-endo-6-yl phenyl sulfone

Chemical Property of endo-6,syn-7-dichlorobicyclo[3.1.1]hept-endo-6-yl phenyl sulfone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of endo-6,syn-7-dichlorobicyclo[3.1.1]hept-endo-6-yl phenyl sulfone

There total 2 articles about endo-6,syn-7-dichlorobicyclo[3.1.1]hept-endo-6-yl phenyl sulfone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

1-(phenylsulfonyl)tricyclo<4.1.0.02,7>heptane (81583-38-2) → 6-(dichloromethyl)cyclohex-1-en-1-yl phenyl sulfone (1114966-10-7) + endo-6,syn-7-dichlorobicyclo[3.1.1]hept-exo-6-yl phenyl sulfone (462648-19-7) + endo-6,syn-7-dichlorobicyclo[3.1.1]hept-endo-6-yl phenyl sulfone (1115244-04-6)

Guidance literature:

With fuming sulfuric acid; sodium carbonate; Nitryl chloride; In chloroform; at 0 ℃; for 1.5h; optical yield given as %de;

DOI:10.1134/S1070428008040106

Reference yield:

1-(phenylsulfonyl)tricyclo<4.1.0.02,7>heptane (81583-38-2) → endo-6,syn-7-dichlorobicyclo[3.1.1]hept-exo-6-yl phenyl sulfone (462648-19-7) + endo-6,syn-7-dichlorobicyclo[3.1.1]hept-endo-6-yl phenyl sulfone (1115244-04-6)

Guidance literature:

With Nitryl chloride; In diethyl ether; optical yield given as %de;

DOI:10.1134/S1070428008040106

upstream raw materials:

1-(phenylsulfonyl)tricyclo<4.1.0.0^2,7>heptane