dimethyl-[4-(1-thioxo-1λ⁵-phospha-4-sila-bicyclo[2.2.2]oct-4-yl)-phenyl]-amine

Base Information

Chemical Name:dimethyl-[4-(1-thioxo-1λ⁵-phospha-4-sila-bicyclo[2.2.2]oct-4-yl)-phenyl]-amine
CAS No.:887626-87-1
Molecular Formula:C₁₄H₂₂NPSSi
Molecular Weight:295.461
Hs Code.:

dimethyl-[4-(1-thioxo-1λ<sup>5</sup>-phospha-4-sila-bicyclo[2.2.2]oct-4-yl)-phenyl]-amine

Synonyms:dimethyl-[4-(1-thioxo-1λ⁵-phospha-4-sila-bicyclo[2.2.2]oct-4-yl)-phenyl]-amine

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of dimethyl-[4-(1-thioxo-1λ⁵-phospha-4-sila-bicyclo[2.2.2]oct-4-yl)-phenyl]-amine

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Technology Process of dimethyl-[4-(1-thioxo-1λ⁵-phospha-4-sila-bicyclo[2.2.2]oct-4-yl)-phenyl]-amine

There total 2 articles about dimethyl-[4-(1-thioxo-1λ⁵-phospha-4-sila-bicyclo[2.2.2]oct-4-yl)-phenyl]-amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: 887626-86-0
4-hydro-1-phospha-4-silabicyclo[2.2.2]octane-1-sulfide

: 698-70-4
4-Iodo-N,N-dimethylaniline

: 887626-87-1
dimethyl-[4-(1-thioxo-1λ⁵-phospha-4-sila-bicyclo[2.2.2]oct-4-yl)-phenyl]-amine

Guidance literature:: With 1-methyl-pyrrolidin-2-one; potassium acetate; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; at 50 ℃; for 10h;
DOI:10.1246/cl.2006.294

Reference yield:

: 578740-42-8
4-phenyl-1-thioxo-1-phospha-4-silabicyclo[2.2.2]octane

: 887626-87-1
dimethyl-[4-(1-thioxo-1λ⁵-phospha-4-sila-bicyclo[2.2.2]oct-4-yl)-phenyl]-amine

Guidance literature:: Multi-step reaction with 2 steps

1.1: TfOH / CH₂Cl₂ / 15 h / 25 °C

1.2: 88 percent / LiAlH₄ / diethyl ether / 24 h / -5 °C

2.1: 63 percent / KOAc; NMP / Pd₂(dba)3*CHCl₃ / 10 h / 50 °C

With 1-methyl-pyrrolidin-2-one; trifluorormethanesulfonic acid; potassium acetate; tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex; In dichloromethane;
DOI:10.1246/cl.2006.294