698-70-4

Basic information

• Product Name: 4-Iodo-N,N-dimethyl-Benzenamine
• Synonyms: 4-Iodo-N,N-dimethyl-Benzenamine;1-DIMETHYLAMINO-4-IODOBENZENE;4-(N,N-DIMETHYLAMINO)IODOBENZENE;N,N-DIMETHYLAMINO-4-IODOANILINE
• CAS NO: 698-70-4
• Molecular Formula: C₈H₁₀IN
• Molecular Weight: 247.0762
• Mol File: 698-70-4.mol
• Article Data: 110

Chemical Properties

• Melting Point: 79.5 °C
• Boiling Point: 263.7°Cat760mmHg
• Flash Point: 113.3°C
• Appearance: /
• Density: 1.652g/cm³
• Vapor Pressure: 0.0101mmHg at 25°C
• Refractive Index: 1.634
• Storage Temp.: Keep in dark place,Sealed in dry,Store in freezer, under -20°C
• PKA: 4.14±0.12(Predicted)
• CAS DataBase Reference: 4-Iodo-N,N-dimethyl-Benzenamine(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Iodo-N,N-dimethyl-Benzenamine(698-70-4)
• EPA Substance Registry System: 4-Iodo-N,N-dimethyl-Benzenamine(698-70-4)

Safety Data

• Hazardous Substances Data: 698-70-4(Hazardous Substances Data)

Usage

Uses

4-Iodo-N,N-dimethylaniline is a useful reactant for organic reactions and the synthesis of various compounds.

InChI:InChI=1/C8H10IN/c1-10(2)8-5-3-7(9)4-6-8/h3-6H,1-2H3

Upstream product

• 121-69-7 N,N-dimethyl-aniline 
• 591-50-4 iodobenzene 
• 13190-50-6 4-dimethylaminophenyllithium 
• 7553-56-2 iodine 
• 64-19-7 acetic acid 
• 586-77-6 4-bromo-N,N-dimethylaniline 
• 67-56-1 methanol 
• 540-37-4 p-aminoiodobenzene 
• 124-38-9 carbon dioxide 
• 60577-34-6 p-iodo-N-methylaniline 
• 159217-89-7 N-Boc-4-iodoaniline 
• 74-88-4 methyl iodide 
• 28611-39-4 4-(dimethylamino)benzene-boronic acid 
• 99-98-9 4-amino-N,N-dimethylaniline 

Downstream Products

• 19095-34-2 (p-iodophenyl)-trimethylammonium iodide 
• 91511-88-5 p-(5-methyl-5-hydroxy-1,3-hexadiynyl)-N,N-dimethylaniline 
• 14301-08-7 N,N-dimethyl-4-(phenylethynyl)aniline 
• 73177-37-4 <4-(Dimethylamino)phenyl>acetone 
• 530-44-9 4-(Dimethylamino)benzophenone 
• 56512-48-2 4-(3-methyl-3-hydroxy-1-butynyl)-N,N-dimethylaniline 
• 18418-79-6 4-(triethoxysilyl)-N,N-dimethylaniline 
• 121-69-7 N,N-dimethyl-aniline 
• 100-23-2 N,N-Dimethyl-4-nitroaniline 
• 7553-56-2 iodine 
• 18840-19-2 (4-(N,N-dimethylaminophenyl))triphenylsilane 
• 77251-02-6 3-(4-Dimethylamino-phenyl)-1,1-diphenyl-prop-2-yn-1-ol 
• 63511-96-6 3-(4'-dimethylaminophenyl)-(E)-propenoic acid methyl ester 
• 943034-07-9 C₂₈H₃₁NOSi 

Relevant articles and documents

Synthesis and crystal structures of imidazolium salts for quadratic optical nonlinearities

We have developed a new organic cation core structure, trans-1-[p-(N, N-dimethylamino) styryl]-3-methylimidozalium for second order nonlinear optical (NLO) applications. Among the eight crystals of imidozalium salts with various counter anions, trans-1-[p

Cobalt-Catalyzed Hydroalkynylation of Vinylaziridines

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Borane-Trimethylamine Complex as a Reducing Agent for Selective Methylation and Formylation of Amines with CO2

We report herein that a borane-trimethylamine complex worked as an efficient reducing agent for the selective methylation and formylation of amines with 1 atm CO2 under metal-free conditions. 6-Amino-2-picoline serves as a highly efficient catalyst for the methylation of various secondary amines, whereas in its absence, the formylation of primary and secondary amines was achieved in high yield with high chemoselectivity. Mechanistic studies suggest that the 6-amino-2-picoline-borane catalytic system operates like an intramolecular frustrated Lewis pair to activate CO2.

Preparation method of N-alkylated derivative of primary amine compound

The invention relates to a preparation method of an N-alkylated derivative of a primary amine compound. The method comprises the following steps: uniformly mixing a primary amine compound, an alcohol compound and a catalyst in a reactor, and heating to react for a period of time to generate an N-alkylated substituted tertiary amine compound; wherein the catalyst is a copper-cobalt bimetallic catalyst, and the carrier of the catalyst is Al2O3. According to the method, alcohol is adopted as an alkylating reagent and is low in price and easy to obtain, a byproduct is water, no pollution is caused to the environment, and the overall reaction atom economy is high; the catalyst is simple in preparation method, low in cost, high in reaction activity and good in structural stability; meanwhile, by using the copper-cobalt bimetallic catalyst, the use of strong base additives can be avoided, and the requirement on reaction equipment is low; and the reaction post-treatment is convenient, and the catalyst can be recycled and is environment-friendly.