2-Diazo-7-methyl-3-oxo-oct-6-enoic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

Base Information

Chemical Name:2-Diazo-7-methyl-3-oxo-oct-6-enoic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester
CAS No.:85720-11-2
Molecular Formula:C₁₉H₃₀N₂O₃
Molecular Weight:334.459
Hs Code.:

Synonyms:2-Diazo-7-methyl-3-oxo-oct-6-enoic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

Suppliers and Price of 2-Diazo-7-methyl-3-oxo-oct-6-enoic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of 2-Diazo-7-methyl-3-oxo-oct-6-enoic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of 2-Diazo-7-methyl-3-oxo-oct-6-enoic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

There total 3 articles about 2-Diazo-7-methyl-3-oxo-oct-6-enoic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 85720-00-9
l-menthyl 7-methyl-3-oxo-6-octenoate

: 85720-11-2
2-Diazo-7-methyl-3-oxo-oct-6-enoic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

Guidance literature:: With 4-toluenesulfonyl azide; triethylamine; In acetonitrile; for 24h; Ambient temperature;
DOI:10.1021/jo00160a028

Reference yield:

: 59557-05-0
(L)-menthyl 3-oxobutyrate

: 85720-11-2
2-Diazo-7-methyl-3-oxo-oct-6-enoic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1) NaH; 2) n-BuLi / 1) THF, 0 deg C, 15 min; 2) hexane, 0 deg C, 15 min; 3) THF, 5-10 deg C, 45 min

2: 99 percent / triethylamine, tosyl azide / acetonitrile / 24 h / Ambient temperature

With n-butyllithium; 4-toluenesulfonyl azide; sodium hydride; triethylamine; In acetonitrile;
DOI:10.1021/jo00160a028

Reference yield:

: 870-63-3
prenyl bromide

: 85720-11-2
2-Diazo-7-methyl-3-oxo-oct-6-enoic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: 1) NaH; 2) n-BuLi / 1) THF, 0 deg C, 15 min; 2) hexane, 0 deg C, 15 min; 3) THF, 5-10 deg C, 45 min

2: 99 percent / triethylamine, tosyl azide / acetonitrile / 24 h / Ambient temperature

With n-butyllithium; 4-toluenesulfonyl azide; sodium hydride; triethylamine; In acetonitrile;
DOI:10.1021/jo00160a028