l-menthyl 7-methyl-3-oxo-6-octenoate

Base Information

Chemical Name:l-menthyl 7-methyl-3-oxo-6-octenoate
CAS No.:85720-00-9
Molecular Formula:C₁₉H₃₂O₃
Molecular Weight:308.461
Hs Code.:

Synonyms:l-menthyl 7-methyl-3-oxo-6-octenoate

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Chemical Property of l-menthyl 7-methyl-3-oxo-6-octenoate

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Technology Process of l-menthyl 7-methyl-3-oxo-6-octenoate

There total 1 articles about l-menthyl 7-methyl-3-oxo-6-octenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 59557-05-0
(L)-menthyl 3-oxobutyrate

: 870-63-3
prenyl bromide

: 85720-00-9
l-menthyl 7-methyl-3-oxo-6-octenoate

Guidance literature:: With n-butyllithium; sodium hydride; Yield given. Multistep reaction; 1) THF, 0 deg C, 15 min; 2) hexane, 0 deg C, 15 min; 3) THF, 5-10 deg C, 45 min;
DOI:10.1021/jo00160a028

Reference yield: 99.0%

: 85720-00-9
l-menthyl 7-methyl-3-oxo-6-octenoate

: 85720-11-2
2-Diazo-7-methyl-3-oxo-oct-6-enoic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester

Guidance literature:: With 4-toluenesulfonyl azide; triethylamine; In acetonitrile; for 24h; Ambient temperature;
DOI:10.1021/jo00160a028

Reference yield:

: 85720-00-9
l-menthyl 7-methyl-3-oxo-6-octenoate

: 85720-03-2
l-menthyl (S)-1-methyl-3-isopropenylcyclopentene-2-carboxylate

Guidance literature:: Multi-step reaction with 4 steps

1: 99 percent / triethylamine, tosyl azide / acetonitrile / 24 h / Ambient temperature

2: 23 percent / copper bronze / toluene / 3 h / Heating

3: 1) potassium tert-butoxide / 1) diisopropyl ether, 30 min; 2) 18 h, reflux

4: 75 percent / p-TsOH / CHCl₃ / 24 h / Ambient temperature

With 4-toluenesulfonyl azide; potassium tert-butylate; copper; toluene-4-sulfonic acid; triethylamine; In chloroform; toluene; acetonitrile;
DOI:10.1021/jo00160a028