2,9-bis-{2-[4-(3,5-bis-benzyloxy-benzyloxy)-phenyl]-ethyl}-[1,10]phenanthroline

Base Information

Chemical Name:2,9-bis-{2-[4-(3,5-bis-benzyloxy-benzyloxy)-phenyl]-ethyl}-[1,10]phenanthroline
CAS No.:691413-54-4
Molecular Formula:C₇₀H₆₀N₂O₆
Molecular Weight:1025.26
Hs Code.:

Synonyms:2,9-bis-{2-[4-(3,5-bis-benzyloxy-benzyloxy)-phenyl]-ethyl}-[1,10]phenanthroline

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Chemical Property of 2,9-bis-{2-[4-(3,5-bis-benzyloxy-benzyloxy)-phenyl]-ethyl}-[1,10]phenanthroline

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Technology Process of 2,9-bis-{2-[4-(3,5-bis-benzyloxy-benzyloxy)-phenyl]-ethyl}-[1,10]phenanthroline

There total 4 articles about 2,9-bis-{2-[4-(3,5-bis-benzyloxy-benzyloxy)-phenyl]-ethyl}-[1,10]phenanthroline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 24131-32-6
3,5-bis(benzyloxy)benzyl bromide

: 691413-58-8
C₂₈H₂₄N₂O₂

: 691413-54-4
2,9-bis-{2-[4-(3,5-bis-benzyloxy-benzyloxy)-phenyl]-ethyl}-[1,10]phenanthroline

Guidance literature:: With 18-crown-6 ether; potassium carbonate; In acetone; for 48h; Heating;
DOI:10.1039/b208719g

Reference yield:

: 484-11-7
2.9-dimethyl-1,10-phenanthroline

: 691413-54-4
2,9-bis-{2-[4-(3,5-bis-benzyloxy-benzyloxy)-phenyl]-ethyl}-[1,10]phenanthroline

Guidance literature:: Multi-step reaction with 3 steps

1.1: LDA / tetrahydrofuran / 3 h / -78 °C

1.2: 36 percent / tetrahydrofuran / 3 h / -78 - 20 °C

2.1: 97 percent / TBAF / tetrahydrofuran / 3 h / 0 °C

3.1: 95 percent / K₂CO₃; 18-crown-6 / acetone / 48 h / Heating

With 18-crown-6 ether; tetrabutyl ammonium fluoride; potassium carbonate; lithium diisopropyl amide; In tetrahydrofuran; acetone;
DOI:10.1039/b208719g

Reference yield:

: 120506-39-0
(4-(bromomethyl)phenoxy) (tert-butyl) dimethylsilane

: 691413-54-4
2,9-bis-{2-[4-(3,5-bis-benzyloxy-benzyloxy)-phenyl]-ethyl}-[1,10]phenanthroline

Guidance literature:: Multi-step reaction with 3 steps

1.1: LDA / tetrahydrofuran / 3 h / -78 °C

1.2: 36 percent / tetrahydrofuran / 3 h / -78 - 20 °C

2.1: 97 percent / TBAF / tetrahydrofuran / 3 h / 0 °C

3.1: 95 percent / K₂CO₃; 18-crown-6 / acetone / 48 h / Heating

With 18-crown-6 ether; tetrabutyl ammonium fluoride; potassium carbonate; lithium diisopropyl amide; In tetrahydrofuran; acetone;
DOI:10.1039/b208719g