2-(Phenylthio)-bicyclo-<2.2.2>-oct-5-en-2-carbonsaeureethylester

Base Information

• Chemical Name: 2-(Phenylthio)-bicyclo-<2.2.2>-oct-5-en-2-carbonsaeureethylester
• CAS No.: 60774-54-1
• Molecular Formula: C₁₇H₂₀O₂S
• Molecular Weight: 288.411
• Mol file: 60774-54-1.mol

Synonyms:2-(Phenylthio)-bicyclo-<2.2.2>-oct-5-en-2-carbonsaeureethylester

Chemical Property of 2-(Phenylthio)-bicyclo-<2.2.2>-oct-5-en-2-carbonsaeureethylester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(Phenylthio)-bicyclo-<2.2.2>-oct-5-en-2-carbonsaeureethylester

There total 1 articles about 2-(Phenylthio)-bicyclo-<2.2.2>-oct-5-en-2-carbonsaeureethylester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

5--bicyclo<2.2.2>octen-(2) (42858-39-9) + diphenyldisulfane (882-33-7) → 2-(Phenylthio)-bicyclo-<2.2.2>-oct-5-en-2-carbonsaeureethylester (60774-54-1)

Guidance literature:

Multistep reaction; (i) LDA, THF, (ii) /BRN= 639794/;

DOI:10.1021/ja00432a034

Reference yield:

2-(Phenylthio)-bicyclo-<2.2.2>-oct-5-en-2-carbonsaeureethylester (60774-54-1) → 2-(Phenylsulfinyl)-bicyclo<2.2.2>-oct-5-en-2-carbonsaeureethylester (60774-70-1)

Guidance literature:

With sodium periodate; In methanol;

DOI:10.1021/ja00432a034

Reference yield:

2-(Phenylthio)-bicyclo-<2.2.2>-oct-5-en-2-carbonsaeureethylester (60774-54-1) → 2-Carboethoxy<2.2.2>bicyclooctadien-2.5 (39863-21-3)

Guidance literature:

Multistep reaction; (i) aq. NaIO₄, MeOH, (ii) (heating);

DOI:10.1021/ja00432a034

upstream raw materials:

5--bicyclo<2.2.2>octen-(2)

diphenyldisulfane

Downstream raw materials:

2-Carboethoxy<2.2.2>bicyclooctadien-2.5

2-(Phenylsulfinyl)-bicyclo<2.2.2>-oct-5-en-2-carbonsaeureethylester