N-allyl-N-{(1R,4R,5S)-4,5-bis-(tert-butyldimethylsilanyloxy)cyclopent-2-enyl}-2-nitrobenzenesulfonamide

Base Information

Chemical Name:N-allyl-N-{(1R,4R,5S)-4,5-bis-(tert-butyldimethylsilanyloxy)cyclopent-2-enyl}-2-nitrobenzenesulfonamide
CAS No.:501415-61-8
Molecular Formula:C₂₆H₄₄N₂O₆SSi₂
Molecular Weight:568.882
Hs Code.:

Synonyms:N-allyl-N-{(1R,4R,5S)-4,5-bis-(tert-butyldimethylsilanyloxy)cyclopent-2-enyl}-2-nitrobenzenesulfonamide

Suppliers and Price of N-allyl-N-{(1R,4R,5S)-4,5-bis-(tert-butyldimethylsilanyloxy)cyclopent-2-enyl}-2-nitrobenzenesulfonamide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of N-allyl-N-{(1R,4R,5S)-4,5-bis-(tert-butyldimethylsilanyloxy)cyclopent-2-enyl}-2-nitrobenzenesulfonamide

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of N-allyl-N-{(1R,4R,5S)-4,5-bis-(tert-butyldimethylsilanyloxy)cyclopent-2-enyl}-2-nitrobenzenesulfonamide

There total 5 articles about N-allyl-N-{(1R,4R,5S)-4,5-bis-(tert-butyldimethylsilanyloxy)cyclopent-2-enyl}-2-nitrobenzenesulfonamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 216015-22-4
(3aS,4R,6aR)-2,2-dimethyl-2H,3aH,4H,6aH-cyclopenta[d][1,3]-dioxol-4-ol

: 501415-61-8
N-allyl-N-{(1R,4R,5S)-4,5-bis-(tert-butyldimethylsilanyloxy)cyclopent-2-enyl}-2-nitrobenzenesulfonamide

Guidance literature:: Multi-step reaction with 4 steps

1: 97 percent / CH₂Cl₂; pyridine / 1 h / 0 °C

2: 95 percent / Et₃N; [Pd₂(dba)3]*CHCl₃; (R,R)-N,N'-bis[2-(PPh₂)benzoyl]-1,2-diaminocyclohexane / tetrahydrofuran / -10 - 0 °C

3: acetic acid / H₂O / 80 - 100 °C

4: imidazole / dimethylformamide

With 1H-imidazole; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; acetic acid; (1R,2R)-1,2-bis[(2-diphenylphosphanyl)benzoylamino]cyclohexane; triethylamine; In tetrahydrofuran; pyridine; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(02)00832-3

Reference yield:

: 65118-17-4
N-allyl-o-nitrobenzenesulfonamide

: 501415-61-8
N-allyl-N-{(1R,4R,5S)-4,5-bis-(tert-butyldimethylsilanyloxy)cyclopent-2-enyl}-2-nitrobenzenesulfonamide

Guidance literature:: Multi-step reaction with 3 steps

1: 95 percent / Et₃N; [Pd₂(dba)3]*CHCl₃; (R,R)-N,N'-bis[2-(PPh₂)benzoyl]-1,2-diaminocyclohexane / tetrahydrofuran / -10 - 0 °C

2: acetic acid / H₂O / 80 - 100 °C

3: imidazole / dimethylformamide

With 1H-imidazole; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; acetic acid; (1R,2R)-1,2-bis[(2-diphenylphosphanyl)benzoylamino]cyclohexane; triethylamine; In tetrahydrofuran; water; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(02)00832-3

Reference yield:

: 501415-58-3
(-)-carbonic acid (1R,4R,5R)-4,5-isopropylidenedioxycyclopent-2-enyl ester methyl ester

: 501415-61-8
N-allyl-N-{(1R,4R,5S)-4,5-bis-(tert-butyldimethylsilanyloxy)cyclopent-2-enyl}-2-nitrobenzenesulfonamide

Guidance literature:: Multi-step reaction with 3 steps

1: 95 percent / Et₃N; [Pd₂(dba)3]*CHCl₃; (R,R)-N,N'-bis[2-(PPh₂)benzoyl]-1,2-diaminocyclohexane / tetrahydrofuran / -10 - 0 °C

2: acetic acid / H₂O / 80 - 100 °C

3: imidazole / dimethylformamide

With 1H-imidazole; tris-(dibenzylideneacetone)dipalladium⁽⁰⁾; acetic acid; (1R,2R)-1,2-bis[(2-diphenylphosphanyl)benzoylamino]cyclohexane; triethylamine; In tetrahydrofuran; water; N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(02)00832-3