1,3-dichloro-2-azulenylbis(4-chlorophenyl)bismuthane

Base Information

• Chemical Name: 1,3-dichloro-2-azulenylbis(4-chlorophenyl)bismuthane
• CAS No.: 827347-44-4
• Molecular Formula: C₂₂H₁₃BiCl₄
• Molecular Weight: 628.138
• Mol file: 827347-44-4.mol

Synonyms:1,3-dichloro-2-azulenylbis(4-chlorophenyl)bismuthane

Chemical Property of 1,3-dichloro-2-azulenylbis(4-chlorophenyl)bismuthane

Chemical Property:

Purity/Quality:

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Technology Process of 1,3-dichloro-2-azulenylbis(4-chlorophenyl)bismuthane

There total 1 articles about 1,3-dichloro-2-azulenylbis(4-chlorophenyl)bismuthane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

chlorobis(4-chlorophenyl)bismuthane (51752-31-9) + 1,3-dichloroazulene (14658-94-7) → 1,3-dichloro-2-azulenylbis(4-chlorophenyl)bismuthane (827347-44-4)

Guidance literature:

With lithium 2,2,6,6-tetramethylpiperidide; In tetrahydrofuran; under Ar atm. to soln. lithium 2,2,6,6-tetramethylpiperidide in THF at -70°C soln. 1,3-dichloroazulene was added, soln. (4-ClC6H4)2BiCl in THF was added and stirred for 5 min; elem. anal.;

DOI:10.1021/om040053f

Reference yield: 68.0%

xenon difluoride (13709-36-9) + 1,3-dichloro-2-azulenylbis(4-chlorophenyl)bismuthane (827347-44-4) → 1,3-dichloro-2-azulenylbis(4-chlorophenyl)bismuth difluoride (827347-47-7)

Guidance literature:

In tetrahydrofuran; under Ar atm. to soln. Bi compound in THF XeF2 was added at 0°C, react. mixt. was stirred for 3 h; soln. was evapd., residue was crystd. from MeOH; elem. anal.;

DOI:10.1021/om040053f

upstream raw materials:

chlorobis(4-chlorophenyl)bismuthane

1,3-dichloroazulene

Downstream raw materials:

1,3-dichloro-2-azulenylbis(4-chlorophenyl)bismuth difluoride

Refernces