Technology Process of Xenon difluoride
There total 71 articles about Xenon difluoride which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
In
neat (no solvent);
Xe and F2 condensed into nickel can (-196°C), warmed (room temp., pressure 34 atm.), preheated electric furnace (400°C) placed around the nickel can (7 h, pressure 78 atm.), quenched to room temp. in water, cooled (-78°C); excess Xe condensed into a storage cylinder (-196°C), evapn. (through a cold trap, -78°C);
- Guidance literature:
-
In
hydrogen fluoride;
HF (liquid); treatment AgF with BF3 in HF, pptn. of AgBF4, adnn. of F2, removal of volatiles, addn. of Hf, BF3 and xenon (condensed in reactor, -100°C), warming to 20°C with stirring (thermal cycling repeated 3-4 times, in 2 h); removal of volatile (vac., -45°C, 5 h), XeF2 (U trap, -78°C); x-ray photography;
DOI:10.1021/ja00168a032
- Guidance literature:
-
With
HF;
In
hydrogen fluoride;
HF (liquid); mixing of AgF2 and BF3 in HF (-100°C), warming(to room temp., stirring), addn. of xenon (stirring 12 h); removal of volatile (-45°C, vac.), XeF2 (U trap, -78°C); x-ray powder photography and Raman spectroscopy; novolatile AgBF4; x-ray powder photography;
DOI:10.1021/ja00168a032
