[Re(2,6-dimethylphenylisocyanide)6](PF₆)

Base Information

• Chemical Name: [Re(2,6-dimethylphenylisocyanide)6](PF₆)
• CAS No.: 87829-87-6
• Molecular Formula: C₅₄H₅₄N₆Re*F₆P
• Molecular Weight: 1118.23
• Mol file: 87829-87-6.mol

Synonyms:[Re(2,6-dimethylphenylisocyanide)6](PF₆)

Chemical Property of [Re(2,6-dimethylphenylisocyanide)6](PF₆)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Re(2,6-dimethylphenylisocyanide)6](PF₆)

There total 3 articles about [Re(2,6-dimethylphenylisocyanide)6](PF₆) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

ammonium hexafluorophosphate + [Re(2,6-dimethylphenylisocyanide)5Cl] (103904-91-2) + 2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) → [Re(2,6-dimethylphenylisocyanide)6](PF6) (87829-87-6)

Guidance literature:

With AgCF₃SO₃; In ethanol; byproducts: AgCl; soln. (Re(2,6-dimethylphenylisocyanide)5Cl) and AgOTf in EtOH was refluxed in the dark for 5-6 h, ppt. was filtered off, 2,6-dimethylphenylisocyanide was added to filtrate and refluxed for 3-4 h, solvent was evapd. in vacuo, aq. soln. NH4PF6 was added; ppt. was filtered, washed with water, and dried in vacuo; elem. anal.;

DOI:10.1021/om049443s

Reference yield: 64.0%

dirhenium(III) dichlorotetra-μ-acetate (33612-87-2,14126-96-6,15628-76-9) + 2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) → [Re(2,6-dimethylphenylisocyanide)6](PF6) (87829-87-6)

Guidance literature:

With potassium hexafluorophosphate; In methanol; acetone; stirring of suspn. in MeOH under reflux for 2 days, addn. of KPF6 in acetone, stirring (30 min); evapn. to dryness, extg. into CH2Cl2, pptg. with petroleum ether, filtn. of white solid, washing (petroleum ether), drying in vac., recrystn. (CH2Cl2/petroleum ether, acetone/Et2O);

Reference yield:

rhenium(I) pentacarbonyl bromide (14220-21-4) + 2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) → [Re(2,6-dimethylphenylisocyanide)6](PF6) (87829-87-6) + {Re(CNC6H3(CH3)2)5Br} (103904-92-3)

Guidance literature:

With NH₄PF₆; palladium(II) oxide; In benzene; >6 equiv 2,6-Me2C6H3NC to (Re(CO)5Br), reflux, anion exchange with NH4PF6; filtn. through cellulose column (acetone); elem. anal.;

DOI:10.1016/0022-328X(89)85366-5

upstream raw materials:

[Re(2,6-dimethylphenylisocyanide)5Cl]

2,6-dimethylphenyl isonitrile

dirhenium(III) dichlorotetra-μ-acetate

rhenium(I) pentacarbonyl bromide

Downstream raw materials:

{Re(CNC₆H₃(CH₃)2)5Br}

[Re(2,6-dimethylphenylisocyanide)5Cl]

[Re(2,6-dimethylphenyl isocyanide)5I]