[Re(2,6-dimethylphenylisocyanide)5Cl]

Base Information

• Chemical Name: [Re(2,6-dimethylphenylisocyanide)5Cl]
• CAS No.: 103904-91-2
• Molecular Formula: C₄₅H₄₅ClN₅Re
• Molecular Weight: 877.546
• Mol file: 103904-91-2.mol

Synonyms:[Re(2,6-dimethylphenylisocyanide)5Cl]

Chemical Property of [Re(2,6-dimethylphenylisocyanide)5Cl]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Re(2,6-dimethylphenylisocyanide)5Cl]

There total 2 articles about [Re(2,6-dimethylphenylisocyanide)5Cl] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

rhenium(I) pentacarbonyl chloride (14099-01-5) + 2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) → [Re(2,6-dimethylphenylisocyanide)5Cl] (103904-91-2)

Guidance literature:

In toluene; Re(CO)5Cl and 2,4-dimethylphenylisocyanide in toluene was refluxed for 5days; ppt. was filtered and washed with ether; elem. anal.;

DOI:10.1021/om049443s

Reference yield:

[Re(2,6-dimethylphenylisocyanide)6](PF6) (87829-87-6) + N-benzyl-N,N,N-triethylammonium chloride (56-37-1) → [Re(2,6-dimethylphenylisocyanide)5Cl] (103904-91-2)

Guidance literature:

In dichloromethane; Irradiation (UV/VIS); irradn. for 6-8 h with a low-pressure Hg arc lamp at 319 nm; evapn., recrystn. (EtOH, Et2O), elem. anal.;

Reference yield: 70.0%

ammonium hexafluorophosphate + [Re(2,6-dimethylphenylisocyanide)5Cl] (103904-91-2) + 2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) → [Re(2,6-dimethylphenylisocyanide)6](PF6) (87829-87-6)

Guidance literature:

With AgCF₃SO₃; In ethanol; byproducts: AgCl; soln. (Re(2,6-dimethylphenylisocyanide)5Cl) and AgOTf in EtOH was refluxed in the dark for 5-6 h, ppt. was filtered off, 2,6-dimethylphenylisocyanide was added to filtrate and refluxed for 3-4 h, solvent was evapd. in vacuo, aq. soln. NH4PF6 was added; ppt. was filtered, washed with water, and dried in vacuo; elem. anal.;

DOI:10.1021/om049443s

upstream raw materials:

[Re(2,6-dimethylphenylisocyanide)6](PF₆)

N-benzyl-N,N,N-triethylammonium chloride

rhenium(I) pentacarbonyl chloride

2,6-dimethylphenyl isonitrile

Downstream raw materials:

[Re(2,6-dimethylphenylisocyanide)6](PF₆)